Silver Nanoparticles Embedded in Gelatin Biopolymer Hydrogel as Catalyst for Reductive Degradation of Pollutants

• Published in: Journal of polymers and the environment 2020-02, Vol.28 (2), p.399-410
• Main Authors: Kamal, Tahseen, Khan, Mohammad Sherjeel Javed, Khan, Sher Bahadar, Asiri, Abdullah M., Chani, Muhammad Tariq Saeed, Ullah, Muhammad Wajid
• Format: Article
• Language: English
• Subjects: Aqueous solutions; Biopolymers; Catalysts; Chemical reduction; Chemistry; Chemistry and Materials Science; Color; Crosslinking; Dyes; Environmental Chemistry; Environmental Engineering/Biotechnology; Gelatin; High temperature; Hydrogels; Industrial Chemistry/Chemical Engineering; Materials Science; Nanoparticles; Nitrophenol; Organic chemistry; Original Paper; Pollutants; Pollution control; Polymer Sciences; Rate constants; Recyclability; Reducing agents; Silver
• ISSN: 1566-2543; 1572-8919
• DOI: 10.1007/s10924-019-01615-8

In the present article, a facile method for the self-synthesis of silver nanoparticles without the use of reducing agent in a gelatin biopolymer hydrogel and its utilization as a catalyst for the pollutants reduction reactions is demonstrated. We first synthesized different wt% of the gelatin aqueous solutions at high temperature followed by crosslinking with formaldehyde solution. Among the three different wt% of the gelatin hydrogels, we found that the 8% hydrogel was suitable for this study. The hydrogel was immersed in a 10 mM AgNO 3 aqueous solution for three days, after which, the gelatin hydrogel changed its color from transparent to brown color indicating the self-formation of the silver nanoparticles inside the gelatin hydrogel (Ag-GL). Importantly, the formation of the nanoparticles did not require any reductant by using this method. The successful preparation of the Ag-GL was confirmed by FESEM, XRD, EDX and TGA analyses. The Ag-GL was tested as catalyst in the reduction reactions of the methyl orange (MO) and 4-nitrophenol (4-NP). Both of these reactions were progressed with high rate constants ( k app  = 0.966 min −1 for MO and 0.621 min −1 for 4-NP were observed). In addition, we discussed the mechanism, influence of the reductant and recyclability of the Ag-GL on the k app of the both reduction reactions. Graphic Abstract Ag nanoparticles were self-synthesized inside a gelatin biopolymer hydrogel without using the harsh chemicals, which were used as hydrogel reactor for hydrogenation of pollutants.