Addition Copolymerization of Silicon-Containing Tricyclononene with 2,5-Norbornadiene Dimer

A series of addition copolymers of 3-trimethylsilyltricyclo[4.2.1.0 2.5 ]non-7-ene with a bifunctional comonomer—2,5-norbornadiene dimer—are synthesized. It is shown that, with the introduction of a small amount of the 2,5-norbornadiene dimer (up to 0.3 mol %), the molecular weight of the polymer in...

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Published in:Polymer science. Series B 2019-11, Vol.61 (6), p.812-816
Main Authors: Alentiev, D. A., Dzhaparidze, D. M., Bermeshev, M. V., Starannikova, L. E., Filatova, M. P., Yampolskii, Yu. P., Finkelshtein, E. Sh
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Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Copolymerization
Copolymers
Crosslinking
Dimers
Functional Polymers
Mechanical properties
Permeability
Polymer Sciences
Polymers
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creator Alentiev, D. A.
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description A series of addition copolymers of 3-trimethylsilyltricyclo[4.2.1.0 2.5 ]non-7-ene with a bifunctional comonomer—2,5-norbornadiene dimer—are synthesized. It is shown that, with the introduction of a small amount of the 2,5-norbornadiene dimer (up to 0.3 mol %), the molecular weight of the polymer increases. When using a large amount of the 2,5-norbornadiene dimer, crosslinked insoluble polymers are formed. As exemplified by a copolymer containing 0.3 mol % 2,5-norbornadiene dimer units, the introduction of the bifunctional comonomer does not lead to a significant decrease in gas permeability, and the developed method can be used to increase the molecular weights of polymers, improve their mechanical properties, and make polymers resistant against plasticization.
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subjects Chemistry
Chemistry and Materials Science
Copolymerization
Copolymers
Crosslinking
Dimers
Functional Polymers
Mechanical properties
Permeability
Polymer Sciences
Polymers
title Addition Copolymerization of Silicon-Containing Tricyclononene with 2,5-Norbornadiene Dimer
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