Synthesis of a novel phosphate‐containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties

A novel poly(methyl methacrylate) (PMMA)‐based copolymer (PMMA‐co‐BDPA) rich in aromatic rings was synthesized via radical copolymerization between a phosphorus‐containing acrylic monomer (BDPA) and methyl methacrylate (MMA). UV‐vis spectroscopy demonstrated that the copolymer had high transparency....

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Published in:Polymers for advanced technologies 2020-03, Vol.31 (3), p.472-481
Main Authors: Yang, Baoping, Wang, Lurong, Guo, Yongliang, Zhang, Yabin, Wang, Niannian, Cui, Jinfeng, Guo, Junhong, Tian, Li
Format: Article
Language:English
Subjects:
Aromatic compounds
Chemical industry
Cone calorimeters
Copolymerization
Copolymers
Differential scanning calorimetry
flame retardancy
Flame retardants
Heat release rate
poly(methyl methacrylate)
Polymethyl methacrylate
Thermal stability
Thermodynamic properties
Thermogravimetric analysis
transparency
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cited_by cdi_FETCH-LOGICAL-c3304-948e2e81d5ee13c5423dde1ab195bcd7af595ff2e414b97e9748461edc99282d3
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container_end_page 481
container_issue 3
container_start_page 472
container_title Polymers for advanced technologies
container_volume 31
creator Yang, Baoping
Wang, Lurong
Guo, Yongliang
Zhang, Yabin
Wang, Niannian
Cui, Jinfeng
Guo, Junhong
Tian, Li
description A novel poly(methyl methacrylate) (PMMA)‐based copolymer (PMMA‐co‐BDPA) rich in aromatic rings was synthesized via radical copolymerization between a phosphorus‐containing acrylic monomer (BDPA) and methyl methacrylate (MMA). UV‐vis spectroscopy demonstrated that the copolymer had high transparency. Thermogravimetric analysis (TGA) and a differential scanning calorimeter (DSC) were used to test the thermal properties of the composites. Additionally, the PMMA‐co‐BDPA‐15 copolymer exhibited a 23% increase in the limited oxygen index (LOI) value. A cone calorimeter test indicated that the peak heat release rate (pk‐HRR) of PMMA‐co‐BDPA was reduced by 29.2% compared with that of pure PMMA, and the carbon yield of burning was obviously increased. The combined test results demonstrated that the prepared copolymer material had good transparency, thermal stability, and flame retardancy.
doi_str_mv 10.1002/pat.4784
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subjects Aromatic compounds
Chemical industry
Cone calorimeters
Copolymerization
Copolymers
Differential scanning calorimetry
flame retardancy
Flame retardants
Heat release rate
poly(methyl methacrylate)
Polymethyl methacrylate
Thermal stability
Thermodynamic properties
Thermogravimetric analysis
transparency
title Synthesis of a novel phosphate‐containing highly transparent PMMA copolymer with enhanced thermal and flame retardant properties
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