Superior full battery performance of tunable hollow N-Doped carbonaceous fibers encapsulating Ni3S2 nanocrystals with enhanced Li/Na storage

• Published in: Electrochimica acta 2020-02, Vol.332, p.135446, Article 135446
• Main Authors: Li, Junzhi, Cao, Junming, Li, Xifei, Sari, Hirbod Maleki Kheimeh, Li, La, Lv, Chunxiao, Zatovsky, Igor V., Han, Wei
• Format: Article
• Language: English
• Subjects: Bacterial leaching; Diffusion rate; Electrochemical analysis; Electrodes; Full-cell; Hollow; Lithium; Lithium-ion batteries; Lithium/sodium ion batteries; Nanocrystals; Nickel sulfide; Nitrogen; N–doped; Rechargeable batteries; Sodium-ion batteries
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2019.135446

A controlled bioleaching strategy to embed Ni3S2 nanocrystals into 1D hollow carbonaceous fibers derived from renewable biomass was designed with enough inner voids as well as abundant natural pyridinic and pyrrolic nitrogen. The hollow fiber-based electrode can prevent the large volume expansion, improve the electronic conductivity and enhance the diffusion rate of Li+/Na+ ion. As a result, the synthesized Ni3S2/hollow carbonaceous fiber electrodes deliver excellent reversible capacity and outstanding cycle stability, i.e., 673.4 mAh g−1 at 0.1 A g−1 after 100 cycles for lithium-ion batteries (LIBs), 378.4 mAh g−1 at 1 A g−1 after 100 cycles for sodium-ion batteries (SIBs), in electrochemical half-cells. More importantly, a superior electrochemical performance is obtained in a full-cell when employing Na3V2(PO4)3 as cathode (i.e., 218.9 mAh g−1 after 100 cycles at 0.5 A g−1). [Display omitted] •A novel controlled bioleaching template-free approach to synthesize tunable hollow Ni3S2 carbonaceous fibers.•1D hollow carbonaceous fibers provide enough inner voids, abundant natural pyridinic and pyrrolic nitrogen.•The composites exhibit excellent lithium/sodium-ion storage performance for Half/Full Cell Applications.