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Investigation of carbon monoxide gas adsorption on the Al2O3/Pd(NO3)2/zeolite composite film

In this study, Al 2 O 3 /Pd(NO 3 ) 2 /zeolite composite films have been fabricated by roll coating method and characterized by X-ray diffraction, energy-dispersive X-ray spectroscopy and field emission scanning electron microscopy. The gas adsorption was tested in an experimental setup by a continuo...

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Published in:Journal of theoretical and applied physics 2020-03, Vol.14 (1), p.65-74
Main Authors: Mozaffari, Nastaran, Haji Seyed Mirzahosseini, Alireza, Sari, Amir Hossein, Fekri Aval, Leila
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description In this study, Al 2 O 3 /Pd(NO 3 ) 2 /zeolite composite films have been fabricated by roll coating method and characterized by X-ray diffraction, energy-dispersive X-ray spectroscopy and field emission scanning electron microscopy. The gas adsorption was tested in an experimental setup by a continuous gas analyzer KIMO KIGAZ 210 at constant temperature and pressure (32 °C and 1.5 bar) and as a function of reaction time (s). The inlet CO gas concentration was 150 mg L −1 , and the saturation level of CO gas concentration was 5 mg L −1 . The maximum adsorption capacity ( q max ) and maximum adsorption efficiency (%) were calculated as 111.16 mg g −1 and 97%, respectively. Pseudo-first-order, pseudo-second-order, and intra-particle diffusion models were investigated to kinetic study of CO adsorption on Al 2 O 3 /Pd(NO 3 ) 2 /zeolite adsorbents. Results indicated that CO adsorption follows the pseudo-second-order model well according to regression coefficient value ( R 2  = 0.98), and the value of pseudo-second-order rate constant of adsorption was obtained as 2 × 10 −5  g mg −1  s −1 . According to the intra-particle diffusion model, adsorption is affected by only one process. So, adsorption of CO by Al 2 O 3 /Pd(NO 3 ) 2 /zeolite adsorbent indicated an effective adsorption by obtained results.
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subjects Adsorbents
Adsorption
Aluminum oxide
Applied and Technical Physics
Atomic
Carbon monoxide
Condensed Matter Physics
Emission analysis
Field emission microscopy
Field emission spectroscopy
Gas analyzers
Medical and Radiation Physics
Molecular
Nanoscale Science and Technology
Optical and Plasma Physics
Particle diffusion
Physics
Physics and Astronomy
Reaction time
Regression analysis
Regression coefficients
Regression models
Roller coating
Zeolites
title Investigation of carbon monoxide gas adsorption on the Al2O3/Pd(NO3)2/zeolite composite film
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