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Electronic polarizability, optical basicity and mechanical properties of aluminum lead phosphate glasses
A series of aluminum, lead phosphate glasses with chemical composition 70P 2 O 5 –5Al 2 O 3 –(25-x) Na 2 O-x PbO, where x = (0, 5, 10, 15, 20 and 25 mol%) have been prepared and synthesized using a conventional melting method. The structural analysis has been performed using FTIR techniques. FT-IR c...
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| Published in: | Optical and quantum electronics 2020-02, Vol.52 (2), Article 125 |
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| Main Authors: | , , , , |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c316t-d060e4bc24cfc725cbfbcf385242536c3f6c5aba825f47e94892b85dc100d2c3 |
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| container_issue | 2 |
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| container_title | Optical and quantum electronics |
| container_volume | 52 |
| creator | Shaaban, Kh. S. Wahab, E. A. Abdel Shaaban, E. R. Yousef, El Sayed Mahmoud, Safwat A. |
| description | A series of aluminum, lead phosphate glasses with chemical composition 70P
2
O
5
–5Al
2
O
3
–(25-x) Na
2
O-x PbO, where x = (0, 5, 10, 15, 20 and 25 mol%) have been prepared and synthesized using a conventional melting method. The structural analysis has been performed using FTIR techniques. FT-IR confirmed that PbO
4
, and AlO
4
are structural units. The optical absorption spectra have been studied and the optical band gap has been estimated. The optical band gap increases with increasing the concentration of PbO. The physical parameters such as density, electronegativity (χ), electron polarizability (α°), optical basicity (˄), molar refractivity R
m
, molar polarizability α
m
, urbach energy (E
u
) and elastic moduli are increased. |
| doi_str_mv | 10.1007/s11082-020-2191-3 |
| format | article |
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2
O
5
–5Al
2
O
3
–(25-x) Na
2
O-x PbO, where x = (0, 5, 10, 15, 20 and 25 mol%) have been prepared and synthesized using a conventional melting method. The structural analysis has been performed using FTIR techniques. FT-IR confirmed that PbO
4
, and AlO
4
are structural units. The optical absorption spectra have been studied and the optical band gap has been estimated. The optical band gap increases with increasing the concentration of PbO. The physical parameters such as density, electronegativity (χ), electron polarizability (α°), optical basicity (˄), molar refractivity R
m
, molar polarizability α
m
, urbach energy (E
u
) and elastic moduli are increased.</description><identifier>ISSN: 0306-8919</identifier><identifier>EISSN: 1572-817X</identifier><identifier>DOI: 10.1007/s11082-020-2191-3</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Absorption spectra ; Aluminum ; Characterization and Evaluation of Materials ; Chemical composition ; Computer Communication Networks ; Electrical Engineering ; Electronegativity ; Energy gap ; Lasers ; Mechanical properties ; Modulus of elasticity ; Optical basicity ; Optical Devices ; Optical properties ; Optics ; Organic chemistry ; Photonics ; Physical properties ; Physics ; Physics and Astronomy ; Refractivity ; Structural analysis</subject><ispartof>Optical and quantum electronics, 2020-02, Vol.52 (2), Article 125</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><rights>2020© Springer Science+Business Media, LLC, part of Springer Nature 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-d060e4bc24cfc725cbfbcf385242536c3f6c5aba825f47e94892b85dc100d2c3</citedby><cites>FETCH-LOGICAL-c316t-d060e4bc24cfc725cbfbcf385242536c3f6c5aba825f47e94892b85dc100d2c3</cites><orcidid>0000-0002-5969-3089</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Shaaban, Kh. S.</creatorcontrib><creatorcontrib>Wahab, E. A. Abdel</creatorcontrib><creatorcontrib>Shaaban, E. R.</creatorcontrib><creatorcontrib>Yousef, El Sayed</creatorcontrib><creatorcontrib>Mahmoud, Safwat A.</creatorcontrib><title>Electronic polarizability, optical basicity and mechanical properties of aluminum lead phosphate glasses</title><title>Optical and quantum electronics</title><addtitle>Opt Quant Electron</addtitle><description>A series of aluminum, lead phosphate glasses with chemical composition 70P
2
O
5
–5Al
2
O
3
–(25-x) Na
2
O-x PbO, where x = (0, 5, 10, 15, 20 and 25 mol%) have been prepared and synthesized using a conventional melting method. The structural analysis has been performed using FTIR techniques. FT-IR confirmed that PbO
4
, and AlO
4
are structural units. The optical absorption spectra have been studied and the optical band gap has been estimated. The optical band gap increases with increasing the concentration of PbO. The physical parameters such as density, electronegativity (χ), electron polarizability (α°), optical basicity (˄), molar refractivity R
m
, molar polarizability α
m
, urbach energy (E
u
) and elastic moduli are increased.</description><subject>Absorption spectra</subject><subject>Aluminum</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical composition</subject><subject>Computer Communication Networks</subject><subject>Electrical Engineering</subject><subject>Electronegativity</subject><subject>Energy gap</subject><subject>Lasers</subject><subject>Mechanical properties</subject><subject>Modulus of elasticity</subject><subject>Optical basicity</subject><subject>Optical Devices</subject><subject>Optical properties</subject><subject>Optics</subject><subject>Organic chemistry</subject><subject>Photonics</subject><subject>Physical properties</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Refractivity</subject><subject>Structural analysis</subject><issn>0306-8919</issn><issn>1572-817X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LwzAYx4MoOKcfwFvAq9G8NG16lDFfYOBlB28hTZM1I2tq0h7mpzezgidPD_z5vzz8ALgl-IFgXD0mQrCgCFOMKKkJYmdgQXhFkSDVxzlYYIZLJGpSX4KrlPYY47LgeAG6tTd6jKF3Gg7Bq-i-VOO8G4_3MAyj08rDRiWnswJV38KD0Z3qf_QhhsHE0ZkEg4XKTwfXTwfojWrh0IU0dGo0cOdVSiZdgwurfDI3v3cJts_r7eoVbd5f3lZPG6QZKUfU4hKbotG00FZXlOvGNtoywWlBOSs1s6XmqlGCcltUpi5ETRvBW50ptFSzJbiba_Nzn5NJo9yHKfZ5UVLGC0oFIWV2kdmlY0gpGiuH6A4qHiXB8sRTzjxl5ilPPCXLGTpnUvb2OxP_mv8PfQMXmnpi</recordid><startdate>20200201</startdate><enddate>20200201</enddate><creator>Shaaban, Kh. S.</creator><creator>Wahab, E. A. Abdel</creator><creator>Shaaban, E. R.</creator><creator>Yousef, El Sayed</creator><creator>Mahmoud, Safwat A.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5969-3089</orcidid></search><sort><creationdate>20200201</creationdate><title>Electronic polarizability, optical basicity and mechanical properties of aluminum lead phosphate glasses</title><author>Shaaban, Kh. S. ; Wahab, E. A. Abdel ; Shaaban, E. R. ; Yousef, El Sayed ; Mahmoud, Safwat A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-d060e4bc24cfc725cbfbcf385242536c3f6c5aba825f47e94892b85dc100d2c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Absorption spectra</topic><topic>Aluminum</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical composition</topic><topic>Computer Communication Networks</topic><topic>Electrical Engineering</topic><topic>Electronegativity</topic><topic>Energy gap</topic><topic>Lasers</topic><topic>Mechanical properties</topic><topic>Modulus of elasticity</topic><topic>Optical basicity</topic><topic>Optical Devices</topic><topic>Optical properties</topic><topic>Optics</topic><topic>Organic chemistry</topic><topic>Photonics</topic><topic>Physical properties</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Refractivity</topic><topic>Structural analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shaaban, Kh. S.</creatorcontrib><creatorcontrib>Wahab, E. A. Abdel</creatorcontrib><creatorcontrib>Shaaban, E. R.</creatorcontrib><creatorcontrib>Yousef, El Sayed</creatorcontrib><creatorcontrib>Mahmoud, Safwat A.</creatorcontrib><collection>CrossRef</collection><jtitle>Optical and quantum electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shaaban, Kh. S.</au><au>Wahab, E. A. Abdel</au><au>Shaaban, E. R.</au><au>Yousef, El Sayed</au><au>Mahmoud, Safwat A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electronic polarizability, optical basicity and mechanical properties of aluminum lead phosphate glasses</atitle><jtitle>Optical and quantum electronics</jtitle><stitle>Opt Quant Electron</stitle><date>2020-02-01</date><risdate>2020</risdate><volume>52</volume><issue>2</issue><artnum>125</artnum><issn>0306-8919</issn><eissn>1572-817X</eissn><abstract>A series of aluminum, lead phosphate glasses with chemical composition 70P
2
O
5
–5Al
2
O
3
–(25-x) Na
2
O-x PbO, where x = (0, 5, 10, 15, 20 and 25 mol%) have been prepared and synthesized using a conventional melting method. The structural analysis has been performed using FTIR techniques. FT-IR confirmed that PbO
4
, and AlO
4
are structural units. The optical absorption spectra have been studied and the optical band gap has been estimated. The optical band gap increases with increasing the concentration of PbO. The physical parameters such as density, electronegativity (χ), electron polarizability (α°), optical basicity (˄), molar refractivity R
m
, molar polarizability α
m
, urbach energy (E
u
) and elastic moduli are increased.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11082-020-2191-3</doi><orcidid>https://orcid.org/0000-0002-5969-3089</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Optical and quantum electronics, 2020-02, Vol.52 (2), Article 125 |
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| language | eng |
| recordid | cdi_proquest_journals_2354228116 |
| source | Springer Link |
| subjects | Absorption spectra Aluminum Characterization and Evaluation of Materials Chemical composition Computer Communication Networks Electrical Engineering Electronegativity Energy gap Lasers Mechanical properties Modulus of elasticity Optical basicity Optical Devices Optical properties Optics Organic chemistry Photonics Physical properties Physics Physics and Astronomy Refractivity Structural analysis |
| title | Electronic polarizability, optical basicity and mechanical properties of aluminum lead phosphate glasses |
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