A hydrophobic semiconducting metal-organic framework assembled from silver chalcogenide wires

Silver chalcogenide wires are assembled for the first time using a linear fluorinated carboxylate ligand into a metal-organic framework (MOF) with multifunctional properties. Fluorinated ligands in the host framework endow the MOF with excellent hydrophobicity. More interestingly, it displays typica...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-02, Vol.56 (14), p.291-294
Main Authors: Wang, Jia-Yin, Li, Wen-Hua, Wei, Zhong, Zhang, Chong, Li, Ya-Hui, Dong, Xi-Yan, Xu, Gang, Zang, Shuang-Quan
Format: Article
Language:English
Subjects:
Chalcogenides
Crystallography
Fluorination
Hydrophobicity
Ligands
Metal-organic frameworks
Semiconductivity
Silver
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Summary:Silver chalcogenide wires are assembled for the first time using a linear fluorinated carboxylate ligand into a metal-organic framework (MOF) with multifunctional properties. Fluorinated ligands in the host framework endow the MOF with excellent hydrophobicity. More interestingly, it displays typical semiconductivity due to the ordered nanoarray of non-discrete helical (-Ag-S-) n chains. Silver chalcogenide wires are for the first time assembled into a rigid framework structure using a fluorinated carboxylate ligand, where electron transfer along Ag-S chains enables semi-conduction.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc08402a