Asymmetric ketone hydroboration catalyzed by alkali metal complexes derived from BINOL ligands

The ability of alkali metal complexes featuring functionalized BINOL-derived ligands to catalyze ketone hydroboration reactions was explored. The reduced products were formed in excellent yields and with variable enantioselectivities dependent upon the nature of the ligand and the alkali metal catio...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2020-02, Vol.49 (8), p.2417-242
Main Authors: Willcox, Darren, Carden, Jamie L, Ruddy, Adam J, Newman, Paul D, Melen, Rebecca L
Format: Article
Language:English
Subjects:
Alkali metal compounds
Chemical reactions
Coordination compounds
Hydroboration
Ligands
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Summary:The ability of alkali metal complexes featuring functionalized BINOL-derived ligands to catalyze ketone hydroboration reactions was explored. The reduced products were formed in excellent yields and with variable enantioselectivities dependent upon the nature of the ligand and the alkali metal cation. The ability of alkali metal complexes bearing chiral BINOL-derived ligands to catalyse the enantioselective hydroboration of ketones was explored.
ISSN:1477-9226
1477-9234
DOI:10.1039/d0dt00232a