The solvent-induced isomerization of silver thiolate clusters with symmetry transformation

A novel ligand-stabilized Ag12 nanocluster was synthesized as a model cluster to investigate the solvent-induced isomerization of Ag12 clusters. Another two novel Ag12 clusters as well as their related symmetry transformations were also successfully obtained through the above solvent-induced isomeri...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-03, Vol.56 (25), p.3649-3652
Main Authors: Chen, Xu-Ran, Yang, Ling, Tan, Yu-Ling, Yu, Hong, Ni, Chun-Yan, Niu, Zheng, Lang, Jian-Ping
Format: Article
Language:English
Subjects:
Clusters
Crystallography
Isomerization
Solvents
Symmetry
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Summary:A novel ligand-stabilized Ag12 nanocluster was synthesized as a model cluster to investigate the solvent-induced isomerization of Ag12 clusters. Another two novel Ag12 clusters as well as their related symmetry transformations were also successfully obtained through the above solvent-induced isomerization process. The solvent-induced isomerizations of Ag12 clusters with symmetry transformations were realized by changing the coordinated solvent molecules at room temperature.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc01195a