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Inorganic–Organic Hybrid Photomechanical Crystals of Azobenzene-modified Polyhedral Oligomeric Silsesquioxane (POSS)

A new class of inorganic–organic hybrid photomechanical material has been created by mono-substitution of polyhedral oligomeric silsesquioxane (POSS) with an azobenzene group via amide bond formation. This compound formed needle-like molecular crystals showing reversible photoinduced bending motions...

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Bibliographic Details
Published in:Chemistry letters 2020-03, Vol.49 (3), p.327-329
Main Authors: Kajiya, Ryota, Wada, Hiroaki, Kuroda, Kazuyuki, Shimojima, Atsushi
Format: Article
Language:English
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Summary:A new class of inorganic–organic hybrid photomechanical material has been created by mono-substitution of polyhedral oligomeric silsesquioxane (POSS) with an azobenzene group via amide bond formation. This compound formed needle-like molecular crystals showing reversible photoinduced bending motions. This finding provides a new design concept of photomechanical materials for various applications.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.190926