In situ investigation of precipitation in aluminium alloys via thermal diffusivity from laser flash analysis

• Published in: Journal of thermal analysis and calorimetry 2020-04, Vol.140 (2), p.725-733
• Main Authors: Kemsies, Richard H., Milkereit, Benjamin, Lindemann, André, Schick, Christoph, Kessler, Olaf
• Format: Article
• Language: English
• Subjects: Aluminum; Aluminum alloys; Aluminum base alloys; Analytical Chemistry; Calorimetry; Chemistry; Chemistry and Materials Science; Comparative analysis; Data processing; Differential scanning calorimetry; Diffusivity; Dispersions; Heating; Inorganic Chemistry; Investigations; Magnesium; Manganese; Measurement methods; Measurement Science and Instrumentation; Physical Chemistry; Polymer Sciences; Specialty metals industry; Thermal diffusivity; Thermal properties
• ISSN: 1388-6150; 1588-2926
• DOI: 10.1007/s10973-019-08880-8

In this work, a commercially available laser flash analysis (LFA) device is used for in situ precipitation monitoring in aluminium alloys by following thermal diffusivity for the first time. The LFA measurement methods and data processing are adapted to allow continuous heating experiments over a wide range of heating rates (0.001–1 K s −1 ). Methods for LFA temperature calibration and thermal lag correction are suggested. Results of continuous heating of Al Mn 0.5 Mg 0.5 aluminium alloy from the as-cast state are compared to in situ differential scanning calorimetry (DSC) and ex situ transmission electron microscopy. It is shown comparing in situ LFA, and DSC substantially improves the interpretation of superimposed reactions, in particular, the precipitation and dissolution of Mn-containing dispersoids and Mg–Si-containing secondary particles.