A Zwitterionic Compound with Heterocyclic Ions as Promising Heat‐Resistant Explosive

A unique zwitterionic compound consisting of functionalized pyrazolate and triazolium ions was synthesized and characterized fully. The zwitterionic compound, 3,5‐dinitro‐4‐(3,4,5‐triamino‐4H‐1,2,4‐triazol‐1‐ium‐1‐yl)‐4H‐pyrazol‐4‐ide (CPTY, 3), exhibits superhigh heat resistance, has a decompositio...

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Published in:Propellants, explosives, pyrotechnics explosives, pyrotechnics, 2020-04, Vol.45 (4), p.531-535
Main Authors: Li, Chuan, Deng, Chenglong, Zhao, Baojing, Wang, Min, Zhang, Man, Zhou, Zhiming
Format: Article
Language:English
Subjects:
Chemical synthesis
crystal structure
Detonation
detonation performance
Heat of formation
Heat resistance
heat-resistant explosive
insensitivity
Thermal resistance
zwitterionic compound
Zwitterions
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cited_by cdi_FETCH-LOGICAL-c3175-4e0dbb7469cc67f1d5b8f3f84b3f87b29f6e3a8b529fafab8d268d5415bff5633
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container_end_page 535
container_issue 4
container_start_page 531
container_title Propellants, explosives, pyrotechnics
container_volume 45
creator Li, Chuan
Deng, Chenglong
Zhao, Baojing
Wang, Min
Zhang, Man
Zhou, Zhiming
description A unique zwitterionic compound consisting of functionalized pyrazolate and triazolium ions was synthesized and characterized fully. The zwitterionic compound, 3,5‐dinitro‐4‐(3,4,5‐triamino‐4H‐1,2,4‐triazol‐1‐ium‐1‐yl)‐4H‐pyrazol‐4‐ide (CPTY, 3), exhibits superhigh heat resistance, has a decomposition temperature of 335 °C, and is insensitive to impact and friction. In addition, owing to its high density (1.82 g cm−3) and positive heat of formation (555.9 kJ mol−1), its detonation velocity and pressure are acceptable high at 8750 m s−1 and 31.5 GPa, respectively. The highly attractive physicochemical and detonation properties of 3 make it promising for use as a heat‐resistant explosive.
doi_str_mv 10.1002/prep.201900415
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subjects Chemical synthesis
crystal structure
Detonation
detonation performance
Heat of formation
Heat resistance
heat-resistant explosive
insensitivity
Thermal resistance
zwitterionic compound
Zwitterions
title A Zwitterionic Compound with Heterocyclic Ions as Promising Heat‐Resistant Explosive
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