Synthesis of 3,3-disubstituted 1-(1H-tetrazol-5-ylmethoxy)triaz-1-ene 2-oxides

3,3-Disubstituted 1-(tetrazol-5-ylmethoxy)triaz-1-ene 2-oxides were synthesized by heating the corresponding 1-cyanomethyl derivatives with sodium azide in DMF. The starting 1-cyanomethyl derivatives were prepared by either the reaction of chloroacetonitrile with the salts of 3,3-disubstituted 1-hyd...

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Bibliographic Details
Published in:Russian chemical bulletin 2020, Vol.69 (1), p.105-109
Main Authors: Smirnov, G. A., Gordeev, P. B., Luk’yanov, O. A.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Derivatives
Full Article
Inorganic Chemistry
Organic Chemistry
Oxides
Sodium azides
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Summary:3,3-Disubstituted 1-(tetrazol-5-ylmethoxy)triaz-1-ene 2-oxides were synthesized by heating the corresponding 1-cyanomethyl derivatives with sodium azide in DMF. The starting 1-cyanomethyl derivatives were prepared by either the reaction of chloroacetonitrile with the salts of 3,3-disubstituted 1-hydroxytriaz-1-ene 2-oxides or successive transformations of these salts to 1-methoxycarbonylmethyl and 1-carbamoylmethyl derivatives and further to 1-cyanomethyl derivatives.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-020-2729-3