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Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change

A propeller-like pyrene derivative of diphenyl-1-pyrenylphosphine (DPPP) is designed and synthesized. DPPP exhibits a unique photo-triggered AIE/ACQ transition with a remarkable third-order nonlinear optical signal change, which is proved to originate from the photo-induced oxidation of a phosphorus...

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Published in:Chemical communications (Cambridge, England) England), 2020-04, Vol.56 (3), p.422-4223
Main Authors: Xing, Chang, Liu, Jianxun, Chen, Fang, Li, Yuanyuan, Lv, Changjian, Peng, Qiuchen, Hou, Hongwei, Li, Kai
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container_title Chemical communications (Cambridge, England)
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creator Xing, Chang
Liu, Jianxun
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Li, Kai
description A propeller-like pyrene derivative of diphenyl-1-pyrenylphosphine (DPPP) is designed and synthesized. DPPP exhibits a unique photo-triggered AIE/ACQ transition with a remarkable third-order nonlinear optical signal change, which is proved to originate from the photo-induced oxidation of a phosphorus atom. A propeller-like pyrene derivative is reported, which exhibits a unique photo-triggered AIE/ACQ transition with a remarkable third-order nonlinear optical signal change.
doi_str_mv 10.1039/d0cc01031f
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Crystallography
Mass spectrometry
NMR
Nonlinear optics
Nuclear magnetic resonance
Optical communication
Oxidation
title Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change
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