Synthesis of an Interrupted AST‐Type Zeolitic Imidazolate Framework

Summary of main observation and conclusion Presented here is a new interrupted AST‐type zeolitic imidazolate framework, Zn5(OH)(dmbim)9(H2O)• 4(DMF) (1) with cub and interrupted ast cages, which exhibits permanent porosity, high hydrophobicity and strong solid‐state photoluminescent properties. More...

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Bibliographic Details
Published in:Chinese journal of chemistry 2020-05, Vol.38 (5), p.449-452
Main Authors: Sun, Yayong, Zhuo, Chao, Wang, Fei, Zhang, Jian
Format: Article
Language:English
Subjects:
Hydrophobicity
Metal-organic frameworks
Photoluminescence
Porosity
Zeolites
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Summary:Summary of main observation and conclusion Presented here is a new interrupted AST‐type zeolitic imidazolate framework, Zn5(OH)(dmbim)9(H2O)• 4(DMF) (1) with cub and interrupted ast cages, which exhibits permanent porosity, high hydrophobicity and strong solid‐state photoluminescent properties. More importantly, structural ordered DMF molecules are firmly confined in the ‐ast cage by strong host‐guest interactions. Presented here is a new zeolitic imidazolate framework with interrupted AST topology and permanent porosity.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201900511