Crystal Structure of S8 Molecule from Thiourea

Sulfur S8 was isolated from a reaction solution of thiourea and bismuth nitrate in N,N-dimethylformamide. The crystal structure was determined by the single-crystal X-ray diffraction method at 90 K. It crystallizes in the orthorhombic space group Fddd with a = 10.3310(8)Å, b = 12.6786(10)Å, c = 24.3...

Full description

Saved in:
Bibliographic Details
Published in:X-ray Structure Analysis Online 2020/01/10, Vol.36, pp.1-2
Main Authors: MIKURIYA, Masahiro, TANIGUCHI, Kazuki, KOYAMA, Yoshiki, WATANABE, Hiroaki, YOSHIOKA, Daisuke, MITSUHASHI, Ryoji, ASATO, Eiji
Format: Article
Language:English
Subjects:
Bismuth
Crystal structure
Molecular structure
Ring structures
Single crystals
Thioureas
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Sulfur S8 was isolated from a reaction solution of thiourea and bismuth nitrate in N,N-dimethylformamide. The crystal structure was determined by the single-crystal X-ray diffraction method at 90 K. It crystallizes in the orthorhombic space group Fddd with a = 10.3310(8)Å, b = 12.6786(10)Å, c = 24.3519(19)Å, V = 3189.7(4)Å3, Dx = 2.136 g/cm3, and Z = 6. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0220 and 0.0570, respectively, for all 1864 independent reflections. The S8 molecule has a crown-shaped ring structure with the α-form.
ISSN:1883-3578
1883-3578
DOI:10.2116/xraystruct.36.1