Structural Diversity of Cationic Copper(II) Complexes with Neutral Nitrogen-Containing Organic Ligands in Compounds with Boron Cluster Anions and Their Derivatives (Review)

Data on the known-to-date copper(II) complexes with neutral nitrogen-containing ligands (2,2'-bipyridyl, 1,10-phenanthroline, 2,2'-bipyridylamine, aminoguanidine, ammonia, pyridine derivatives, etc.) with boron cluster anions, including those containing bridging OH – and groups, are genera...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2020-04, Vol.65 (4), p.514-534
Main Authors: Avdeeva, V. V., Malinina, E. A., Zhizhin, K. Yu, Kuznetsov, N. T.
Format: Article
Language:English
Subjects:
Ammonia
Anions
Boron
Boron compounds
Chemistry
Chemistry and Materials Science
Clusters
Complex compounds
Coordination Compounds
Copper
Copper compounds
Derivatives
Inorganic Chemistry
Ligands
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Summary:Data on the known-to-date copper(II) complexes with neutral nitrogen-containing ligands (2,2'-bipyridyl, 1,10-phenanthroline, 2,2'-bipyridylamine, aminoguanidine, ammonia, pyridine derivatives, etc.) with boron cluster anions, including those containing bridging OH – and groups, are generalized. Mono-, di-, tri-, tetranuclear, and polymer copper(II) complexes are considered; the geometry of copper(II) coordination polyhedra, structural features of complex compounds, and methods for their preparation are discussed. The boron cluster anions [B 10 H 10 ] 2– , [B 12 H 12 ] 2– , [B 10 Cl 10 ] 2– , [B 20 H 18 ] 2– and their derivatives (substituted derivatives, carboranes, and metallacarboranes) have been chosen as counterions.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023620040026