Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments. Herein we report th...

Full description

Saved in:
Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2020-05, Vol.22 (1), p.379-382
Main Authors: Das, Uttam Kumar, Janes, Trevor, Kumar, Amit, Milstein, David
Format: Article
Language:English
Subjects:
Amines
Coordination compounds
Diols
Green chemistry
Hydrogenation
Imides
Manganese
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments. Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex.
ISSN:1463-9262
1463-9270
DOI:10.1039/d0gc00570c