Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments. Herein we report th...

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Published in:Green chemistry : an international journal and green chemistry resource : GC 2020-05, Vol.22 (1), p.379-382
Main Authors: Das, Uttam Kumar, Janes, Trevor, Kumar, Amit, Milstein, David
Format: Article
Language:English
Subjects:
Amines
Coordination compounds
Diols
Green chemistry
Hydrogenation
Imides
Manganese
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description Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments. Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex.
doi_str_mv 10.1039/d0gc00570c
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source Royal Society of Chemistry
subjects Amines
Coordination compounds
Diols
Green chemistry
Hydrogenation
Imides
Manganese
title Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines
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