Kinetic and Thermodynamic Analysis of Guaiacol Hydrodeoxygenation

Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported Mo x C–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 °C and 300 °C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of ad...

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Published in:Catalysis letters 2019-09, Vol.149 (9), p.2453-2467
Main Authors: Sulman, Alexandrina, Mäki-Arvela, Päivi, Bomont, Louis, Alda-Onggar, Moldir, Fedorov, Vyacheslav, Russo, Vincenzo, Eränen, Kari, Peurla, Markus, Akhmetzyanova, Uliana, Skuhrovcová, Lenka, Tišler, Zdeněk, Grénman, Henrik, Wärnå, Johan, Murzin, Dmitry Yu
Format: Article
Language:English
Subjects:
Analysis
Catalysis
Catalysts
Chemistry
Chemistry and Materials Science
Deoxygenation
Hydrogen
Industrial Chemistry/Chemical Engineering
Oligomers
Organometallic Chemistry
Phenols
Physical Chemistry
Reaction kinetics
Thermodynamics
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cited_by cdi_FETCH-LOGICAL-c436t-9a84bd15047e041932722008d74db0bd92ed361d5cb159359db8ac8fff01711c3
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container_title Catalysis letters
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creator Sulman, Alexandrina
Mäki-Arvela, Päivi
Bomont, Louis
Alda-Onggar, Moldir
Fedorov, Vyacheslav
Russo, Vincenzo
Eränen, Kari
Peurla, Markus
Akhmetzyanova, Uliana
Skuhrovcová, Lenka
Tišler, Zdeněk
Grénman, Henrik
Wärnå, Johan
Murzin, Dmitry Yu
description Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported Mo x C–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 °C and 300 °C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo 2 C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done. Graphic Abstract
doi_str_mv 10.1007/s10562-019-02856-x
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1572-879X
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source Springer Nature
subjects Analysis
Catalysis
Catalysts
Chemistry
Chemistry and Materials Science
Deoxygenation
Hydrogen
Industrial Chemistry/Chemical Engineering
Oligomers
Organometallic Chemistry
Phenols
Physical Chemistry
Reaction kinetics
Thermodynamics
title Kinetic and Thermodynamic Analysis of Guaiacol Hydrodeoxygenation
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