Structural characterization of HPM-7, a more ordered than expected germanosilicate zeolite

• Published in: Dalton transactions : an international journal of inorganic chemistry 2020-06, Vol.49 (21), p.737-743
• Main Authors: Lu, Peng, Zhang, Yaping, Mayoral, Alvaro, Gómez-Hortigüela, Luis, Camblor, Miguel A
• Format: Article
• Language: English
• Subjects: Stacking faults; Structural analysis; Topology; X ray powder diffraction; Zeolites
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d0dt00818d

HPM-7, a germanosilicate synthesized using long imidazolium-based dications with two different linkers, is shown to possess the POS topology, although disorder may exist but it is very difficult to discern. First, three simple ordered polymorphs (POS-A to POS-C) with very similar energies and structural motifs could give rise to intergrowths that would be very difficult to recognize by powder X-ray diffraction, according to DIFFaX simulations. Another four structures (POS-D to POS-G) can be derived from POS by changing the orientation of two single four rings within the structure, possibly providing an additional source of disorder. While 3D EDT strongly suggests that HPM-7 basically possesses the POS-A ( i.e. POS) topology, a detailed HR-STEM study demonstrates the rare existence of some disorder compatible with the polymorph POS-D. The general avoidance of polymorphs with very similar structural motifs and comparable energies points to a rather specific structure-direction by the organic dications used. Although several feasible polymorphs of similar energy and structural motifs could exist, the zeolite HPM-7 possesses a remarkably ordered crystalline structure.