Organocatalytic 1,5-trifluoromethylthio-sulfonylation of vinylcyclopropane mediated by visible light in the water phase

1,2-Difunctionalization has developed into a robust tool for the preparation of complex organic molecules, and remote difunctionalization has also aroused widespread interest to achieve pluripotency of difunctionalization. Herein, we report a metal-free organocatalytic system mediated by visible lig...

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Bibliographic Details
Published in:Organic chemistry frontiers an international journal of organic chemistry 2020-06, Vol.7 (11), p.1314-1320
Main Authors: Liu, Junkai, Yao, Hong, Li, Xinnan, Wu, Hongyu, Lin, Aijun, Yao, Hequan, Xu, Jinyi, Xu, Shengtao
Format: Article
Language:English
Subjects:
Crystallography
Functional groups
Organic chemistry
Pluripotency
Reagents
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Summary:1,2-Difunctionalization has developed into a robust tool for the preparation of complex organic molecules, and remote difunctionalization has also aroused widespread interest to achieve pluripotency of difunctionalization. Herein, we report a metal-free organocatalytic system mediated by visible light to realize the remote 1,5-trifluoromethylthio-sulfonylation of vinylcyclopropane with ArSO2SCF3 reagents in the water phase. This reaction exhibits broad functional group compatibility, moderate to good yields, and high regioselectivities and stereoselectivities.
ISSN:2052-4110
2052-4110
DOI:10.1039/d0qo00343c