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Composition and Electronic and Atomic Structure of Palladium Nanoparticles at Different Metal Concentrations in a Polyethylene Matrix

The composition and the electronic and atomic structure of palladium nanoparticles stabilized in high-pressure polyethylene (with 10 and 20 wt % palladium) have been studied using transmission electron microscopy, X-ray diffraction, and X-ray absorption spectroscopy. It has been found that these nan...

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Published in:Technical physics letters 2020-04, Vol.46 (4), p.323-326
Main Authors: Podsukhina, S. S., Kozinkin, A. V., Vlasenko, V. G., Yurkov, G. Yu, Popkov, O. V.
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description The composition and the electronic and atomic structure of palladium nanoparticles stabilized in high-pressure polyethylene (with 10 and 20 wt % palladium) have been studied using transmission electron microscopy, X-ray diffraction, and X-ray absorption spectroscopy. It has been found that these nanoparticles have metallic (Pd) and oxide (Pd 2 O 3 ) components, and their mean size and coordination numbers in the Pd sphere decrease from 7 to 6 nm and from 7 to 5.7, respectively, together with the metal concentration.
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subjects Atomic structure
Classical and Continuum Physics
Composition
Coordination numbers
Nanoparticles
Palladium
Physics
Physics and Astronomy
Polyethylene
Polyethylenes
X ray absorption
title Composition and Electronic and Atomic Structure of Palladium Nanoparticles at Different Metal Concentrations in a Polyethylene Matrix
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