Large-scale synthesis of cesium lead halide perovskite nanocrystals for zinc ion detection

Quantum dots of halide perovskite are considered to be the promising candidates for optoelectronic applications. Although many methods have been developed to prepare CsPbX 3 (X = Cl, Br, I) nanocrystals, the large-scale synthesis of CsPbX 3 nanocrystals remains an outstanding challenge. In this pape...

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Bibliographic Details
Published in:Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2020-06, Vol.22 (6), Article 153
Main Authors: Guo, Jiaqing, Ye, Shuai, Song, Jun, Qu, Junle
Format: Article
Language:English
Subjects:
Cesium
Characterization and Evaluation of Materials
Chemistry and Materials Science
Crystals
Inorganic Chemistry
Lasers
Lead compounds
Luminescence
Materials Science
Metal halides
Morphology
Nanocrystals
Nanoparticles
Nanotechnology
Nucleation
Optical Devices
Optics
Optoelectronics
Perovskites
Photoluminescence
Photonics
Photons
Physical Chemistry
Precursors
Quantum dots
Research Paper
Selectivity
Zinc
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Summary:Quantum dots of halide perovskite are considered to be the promising candidates for optoelectronic applications. Although many methods have been developed to prepare CsPbX 3 (X = Cl, Br, I) nanocrystals, the large-scale synthesis of CsPbX 3 nanocrystals remains an outstanding challenge. In this paper, nanocrystals of CsPbBr 3 were subjected to one-pot synthesis in octane by using a precursor with a high concentration. CsPbBr 3 nanocrystals were obtained in octane dispersion as well as in the precipitation. All obtained nanocrystals were in the CsPbBr 3 nanocubes with uniform morphologies and average size of 7.8 nm, and featured the same emission peak and photoluminescence quantum yield (PLQY), which indicated that the concentration of the precursor did not influence the nucleation of the CsPbBr 3 nanocrystals. This result implied a large-scale synthesis of the nanocrystals. Following this, ~ 1 g of CsPbBr 3 nanocrystals were obtained only in the 10-mL octane solution when the concentration of PbBr 2 was up to 0.3 mol/L. This one-pot process was suitable for the large-scale and cost-effective synthesis of CsPbX 3 nanocrystals. Besides, the obtained CsPbBr 3 nanocrystals were used as probes of the [Zn 2+ ] detection for the first time. It was found that the Zn 2+ ions could quench the photoluminescence intensity of CsPbX 3 nanocrystals and the quench effect showed high selectivity and high anti-interference.
ISSN:1388-0764
1572-896X
DOI:10.1007/s11051-020-04887-7