Probing electrochemical reactivity in an Sb2S3-containing potassium-ion battery anode: observation of an increased capacity

Potassium-ion batteries are attracting considerable attention as a viable type of high voltage battery. Among available anode materials, composites containing Sb2S3 are some of the most interesting high capacity candidates. A nanostructured Sb2S3–reduced graphene oxide composite anode material is ev...

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Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2020-06, Vol.8 (22), p.11424-11434
Main Authors: Lakshmi, V, Mikhaylov, Alexey A, Medvedev, Alexander G, Zhang, Chao, Thrinathreddy Ramireddy, Rahman, Md Mokhlesur, Cizek, Pavel, Golberg, Dmitri, Chen, Ying, Ovadia Lev, Prikhodchenko, Petr V, Glushenkov, Alexey M
Format: Article
Language:English
Subjects:
Anodes
Antimony
Antimony base alloys
Batteries
Composite materials
Electrochemistry
Electrode materials
Electrodes
Electrolytes
Graphene
High voltage
Intermediates
Potassium
Reaction mechanisms
Reaction products
Rechargeable batteries
Tin disulfide
Transmission electron microscopy
X-ray diffraction
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Summary:Potassium-ion batteries are attracting considerable attention as a viable type of high voltage battery. Among available anode materials, composites containing Sb2S3 are some of the most interesting high capacity candidates. A nanostructured Sb2S3–reduced graphene oxide composite anode material is evaluated in this study and compared with a structurally similar SnS2–reduced graphene oxide material reported previously by this team. The behaviour of the Sb2S3-based electrodes is assessed in both 1 M KPF6 in ethylene carbonate–diethyl carbonate and 1 M KPF6 in 1,2-dimethoxyethane electrolytes. Depotassiation capacities in excess of 650 mA h g−1 are recorded for the composite electrodes, superior not only to SnS2-based electrodes but also to all previously reported Sb2S3-containing electrode materials for potassium-ion batteries. In order to establish insights into the reaction mechanism of the Sb2S3 phase with potassium, post-cycling X-ray diffraction and in situ transmission electron microscopy are utilised. The recorded data suggest the presence of antimony alloys and potassium polysulphides as reaction products and intermediates; a possible conversion-alloying reaction mechanism is discussed. The results indicate that a capacity higher than previously believed is achievable in the Sb2S3 active component of potassium-ion battery electrodes.
ISSN:2050-7488
2050-7496
DOI:10.1039/d0ta03555f