Xanthylium, Thioxanthylium, and Tropylium Salts in Reactions with Imidazole and Benzimidazole

Xanthylium, thioxanthylium, or tropylium salts were reacted with imidazole and benzimidazole. The reactions gave the substitution products of the secondary amino hydrogen atoms in the imidazole and benzimidazole heterorings by xanthyl, thioxanthyl, and tropylium fragments. The structure of the obtai...

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Published in:Russian journal of organic chemistry 2020-05, Vol.56 (5), p.828-832
Main Authors: Yunnikova, L. P., Likhareva, Yu. E., Islyaykin, M. K., Danilova, E. A.
Format: Article
Language:English
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Chemistry
Chemistry and Materials Science
Hydrogen atoms
Imidazole
Mass spectrometry
NMR spectroscopy
Organic Chemistry
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description Xanthylium, thioxanthylium, or tropylium salts were reacted with imidazole and benzimidazole. The reactions gave the substitution products of the secondary amino hydrogen atoms in the imidazole and benzimidazole heterorings by xanthyl, thioxanthyl, and tropylium fragments. The structure of the obtained compounds was established by mass spectrometry, 1 H NMR spectroscopy, and X-ray diffraction analysis.
doi_str_mv 10.1134/S1070428020050152
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subjects Chemistry
Chemistry and Materials Science
Hydrogen atoms
Imidazole
Mass spectrometry
NMR spectroscopy
Organic Chemistry
title Xanthylium, Thioxanthylium, and Tropylium Salts in Reactions with Imidazole and Benzimidazole
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