Two-dimensional FTIR spectroscopic analysis of crystallization in cross-linked poly(ether ether ketone)

2D-COS–FTIR was used to locate the crystallization-sensitive bands of ion-irradiated poly(ether ether ketone). The band at 1310 cm −1 was the most sensitive band, and the area under this band changed linearly with the degree of crystallization which was obtained from differential scanning calorimetr...

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Published in:International journal of plastics technology 2020-12, Vol.24 (1-2), p.1-8
Main Authors: Al Lafi, Abdul G., Alzier, Ali, Allaf, Abdul W.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Crosslinking
Crystallization
Crystals
Fourier transforms
Infrared spectroscopy
Irradiation
Materials Science
Polyether ether ketones
Polymer Sciences
Research Article
Two dimensional analysis
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Alzier, Ali
Allaf, Abdul W.
description 2D-COS–FTIR was used to locate the crystallization-sensitive bands of ion-irradiated poly(ether ether ketone). The band at 1310 cm −1 was the most sensitive band, and the area under this band changed linearly with the degree of crystallization which was obtained from differential scanning calorimetry. The deviation between experimentally determined and calculated degree of crystallization progressively increased at irradiation doses above 20 MGy for proton and helium-irradiated PEEK. This was attributed to different cross-linking mechanism on irradiation with the two different ions. 2D-COS–FTIR spectroscopy is a powerful tool for polymer characterization and helps in the quantitative analysis.
doi_str_mv 10.1007/s12588-019-09254-3
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source SpringerLINK Contemporary 1997-Present
subjects Chemistry
Chemistry and Materials Science
Crosslinking
Crystallization
Crystals
Fourier transforms
Infrared spectroscopy
Irradiation
Materials Science
Polyether ether ketones
Polymer Sciences
Research Article
Two dimensional analysis
title Two-dimensional FTIR spectroscopic analysis of crystallization in cross-linked poly(ether ether ketone)
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