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RETRACTED ARTICLE: Two novel nanostructured La(III) coordination polymers were synthesized by sonochemical: crystal structures along with anticancer activity on human nasopharyngeal carcinoma cells

The preparation and the structural characterization of two La(III)-based coordination polymers was described in this study, in which {[La(H 2 O)(BTCTB)]·2H 2 O} n ( 1 , H 3 BTCTB = 3,3′,3′′-[1,3,5‐benzenetriyltris(carbonyl amino)] three benzoic acid) and [(La 2 (TATAB) 2 )·4DMF·4H 2 O] n ( 2 , H 3 T...

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Published in:Journal of the Iranian Chemical Society 2020, Vol.17 (9), p.2307-2316
Main Authors: Cui, Zhong-Tao, Liu, Hong, Yuan, Yao-Wei, Wang, Xiao-Hui, Tang, Jian-Ming, Chu, Po-Yi, Zhang, Ye
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description The preparation and the structural characterization of two La(III)-based coordination polymers was described in this study, in which {[La(H 2 O)(BTCTB)]·2H 2 O} n ( 1 , H 3 BTCTB = 3,3′,3′′-[1,3,5‐benzenetriyltris(carbonyl amino)] three benzoic acid) and [(La 2 (TATAB) 2 )·4DMF·4H 2 O] n ( 2 , H 3 TATAB = 4,4,4″s-triazine-1,3,5-triethyl-m-aminobenzoic acid) were prepared by means of two flexible tricarboxylic acid ligands with different joints and functional backbones. Moreover, a sonochemical synthesis way has been carried out to produce the nanostructures of complexes 1 and 2 . In addition, their anticancer activity was evaluated on nasopharyngeal carcinoma cells. Firstly, Cell Counting Kit-8 test kit was used to test the cancer cells proliferation after treated with nano 1 or 2 . Then, the Annexin V-FITC/PI test was performed and the percentage of the apoptotic cancer cells was determined after nano 1 and 2 treatment. Next, the ROS accumulation after nano 1 and 2 treatment was detected by DCFH-DA detection kit. Finally, the expression level of FHIT in nasopharyngeal carcinoma cells treated with nano 1 and 2 was evaluated via western blot.
doi_str_mv 10.1007/s13738-020-01926-x
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subjects Analytical Chemistry
Anticancer properties
Benzoic acid
Biochemistry
Cancer
Carbonyls
Chemistry
Chemistry and Materials Science
Coordination polymers
Crystal structure
Inorganic Chemistry
Organic Chemistry
Original Paper
Physical Chemistry
Polyimide resins
Structural analysis
title RETRACTED ARTICLE: Two novel nanostructured La(III) coordination polymers were synthesized by sonochemical: crystal structures along with anticancer activity on human nasopharyngeal carcinoma cells
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