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A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties
1-D chain coordination polymer (CP) of [Cu 2 I 2 (PymPPh 2 )] n type has been synthesized reacting CuI with 2-(diphenylphosphino)pyrimidine (PymPPh 2 ) under mild conditions (MeCN, r.t.). The structure of the CP is imagined by double-stranded (Cu 2 I 2 ) n ribbons, the Cu atoms of which are bridged...
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| Published in: | Journal of structural chemistry 2020-06, Vol.61 (6), p.894-898 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c316t-5d44de2df89ab740c700531b446eab57102531cc4335475bbfc7d74ce8b73ba13 |
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| cites | cdi_FETCH-LOGICAL-c316t-5d44de2df89ab740c700531b446eab57102531cc4335475bbfc7d74ce8b73ba13 |
| container_end_page | 898 |
| container_issue | 6 |
| container_start_page | 894 |
| container_title | Journal of structural chemistry |
| container_volume | 61 |
| creator | Davydova, M. P. Rakhmanova, M. I. Bagryanskaya, I. Yu Brylev, K. A. Artem’ev, A. V. |
| description | 1-D chain coordination polymer (CP) of [Cu
2
I
2
(PymPPh
2
)]
n
type has been synthesized reacting CuI with 2-(diphenylphosphino)pyrimidine (PymPPh
2
) under mild conditions (MeCN, r.t.). The structure of the CP is imagined by double-stranded (Cu
2
I
2
)
n
ribbons, the Cu atoms of which are bridged by the PymPPh
2
ligands in a 1,3-
N,P
fashion. At ambient temperature the solid-state CP manifests broad-band photoluminescence (λ
max
= 530 nm) with the average lifetime of 1.2 µs and quantum efficiency being 15%. |
| doi_str_mv | 10.1134/S0022476620060086 |
| format | article |
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2
I
2
(PymPPh
2
)]
n
type has been synthesized reacting CuI with 2-(diphenylphosphino)pyrimidine (PymPPh
2
) under mild conditions (MeCN, r.t.). The structure of the CP is imagined by double-stranded (Cu
2
I
2
)
n
ribbons, the Cu atoms of which are bridged by the PymPPh
2
ligands in a 1,3-
N,P
fashion. At ambient temperature the solid-state CP manifests broad-band photoluminescence (λ
max
= 530 nm) with the average lifetime of 1.2 µs and quantum efficiency being 15%.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476620060086</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Ambient temperature ; Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Optical properties ; Photoluminescence ; Physical Chemistry ; Quantum efficiency ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2020-06, Vol.61 (6), p.894-898</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-5d44de2df89ab740c700531b446eab57102531cc4335475bbfc7d74ce8b73ba13</citedby><cites>FETCH-LOGICAL-c316t-5d44de2df89ab740c700531b446eab57102531cc4335475bbfc7d74ce8b73ba13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Davydova, M. P.</creatorcontrib><creatorcontrib>Rakhmanova, M. I.</creatorcontrib><creatorcontrib>Bagryanskaya, I. Yu</creatorcontrib><creatorcontrib>Brylev, K. A.</creatorcontrib><creatorcontrib>Artem’ev, A. V.</creatorcontrib><title>A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>1-D chain coordination polymer (CP) of [Cu
2
I
2
(PymPPh
2
)]
n
type has been synthesized reacting CuI with 2-(diphenylphosphino)pyrimidine (PymPPh
2
) under mild conditions (MeCN, r.t.). The structure of the CP is imagined by double-stranded (Cu
2
I
2
)
n
ribbons, the Cu atoms of which are bridged by the PymPPh
2
ligands in a 1,3-
N,P
fashion. At ambient temperature the solid-state CP manifests broad-band photoluminescence (λ
max
= 530 nm) with the average lifetime of 1.2 µs and quantum efficiency being 15%.</description><subject>Ambient temperature</subject><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Optical properties</subject><subject>Photoluminescence</subject><subject>Physical Chemistry</subject><subject>Quantum efficiency</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEQhoMoWKs_wFvAi4Kr-drNrre69aNQsFA9L9ls1qa0yZpkD4t_3tQKHsTTMDPv877MAHCO0Q3GlN0uESKE8SwjCGUI5dkBGOGU0yTnvDgEo9062e2PwYn3a4RQkRfZCHxOIJ7C0lrXaCOCtgYu7GbYKgfvhVcNjIOyn0FhGkiSy6nuVsoMm25lfbfSxl4tBqe3OsLqDi4HE1bKa38Nl8H1MvROfZPzfhsFXioT4MLZTrmglT8FR63YeHX2U8fg7fHhtXxO5i9Ps3IyTyTFWUjShrFGkabNC1FzhiRHKKW4ZixTok45RiS2UjJKU8bTum4lbziTKq85rQWmY3Cx9-2c_eiVD9Xa9s7EyIqwGBHdChpVeK-SznrvVFt18TLhhgqjavfj6s-PI0P2jI9a867cr_P_0BcHS339</recordid><startdate>20200601</startdate><enddate>20200601</enddate><creator>Davydova, M. P.</creator><creator>Rakhmanova, M. I.</creator><creator>Bagryanskaya, I. Yu</creator><creator>Brylev, K. A.</creator><creator>Artem’ev, A. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200601</creationdate><title>A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties</title><author>Davydova, M. P. ; Rakhmanova, M. I. ; Bagryanskaya, I. Yu ; Brylev, K. A. ; Artem’ev, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-5d44de2df89ab740c700531b446eab57102531cc4335475bbfc7d74ce8b73ba13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Ambient temperature</topic><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Optical properties</topic><topic>Photoluminescence</topic><topic>Physical Chemistry</topic><topic>Quantum efficiency</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Davydova, M. P.</creatorcontrib><creatorcontrib>Rakhmanova, M. I.</creatorcontrib><creatorcontrib>Bagryanskaya, I. Yu</creatorcontrib><creatorcontrib>Brylev, K. A.</creatorcontrib><creatorcontrib>Artem’ev, A. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Davydova, M. P.</au><au>Rakhmanova, M. I.</au><au>Bagryanskaya, I. Yu</au><au>Brylev, K. A.</au><au>Artem’ev, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2020-06-01</date><risdate>2020</risdate><volume>61</volume><issue>6</issue><spage>894</spage><epage>898</epage><pages>894-898</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>1-D chain coordination polymer (CP) of [Cu
2
I
2
(PymPPh
2
)]
n
type has been synthesized reacting CuI with 2-(diphenylphosphino)pyrimidine (PymPPh
2
) under mild conditions (MeCN, r.t.). The structure of the CP is imagined by double-stranded (Cu
2
I
2
)
n
ribbons, the Cu atoms of which are bridged by the PymPPh
2
ligands in a 1,3-
N,P
fashion. At ambient temperature the solid-state CP manifests broad-band photoluminescence (λ
max
= 530 nm) with the average lifetime of 1.2 µs and quantum efficiency being 15%.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476620060086</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2020-06, Vol.61 (6), p.894-898 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_proquest_journals_2431605393 |
| source | Springer Nature |
| subjects | Ambient temperature Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Coordination polymers Inorganic Chemistry Molecular Optical and Plasma Physics Optical properties Photoluminescence Physical Chemistry Quantum efficiency Solid State Physics |
| title | A 1D Coordination Polymer Based on CuI and 2-(Diphenylphosphino)Pyrimidine: Synthesis, Structure and Luminescent Properties |
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