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Synthesis, crystal structure, thermal studies and antimicrobial activity of a new chelate complex of copper(II) succinate with N,N,N′,N′-tetramethylethylenediamine
A coordination polymer, [Cu(tmen)(succ)] n ·4nH 2 O (1) (where succ 2- = succinate dianion, tmen = N,N,N′,N′-tetramethylethylenediamine), was prepared by reacting CuCl 2 ·2H 2 O, succinic acid (H 2 succin) and tmen, and was characterized by elemental analysis, UV-visible spectroscopy, FTIR spectrosc...
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| Published in: | Journal of coordination chemistry 2020-06, Vol.73 (12), p.1778-1789 |
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| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c338t-e549733bb994cc7627f191da34c16f2d037123e88069354a6cc9b37e896d74413 |
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| cites | cdi_FETCH-LOGICAL-c338t-e549733bb994cc7627f191da34c16f2d037123e88069354a6cc9b37e896d74413 |
| container_end_page | 1789 |
| container_issue | 12 |
| container_start_page | 1778 |
| container_title | Journal of coordination chemistry |
| container_volume | 73 |
| creator | Batool, Syeda Shahzadi Gilani, Syeda Rubina Zainab, Syeda Sakina Tahir, Muhammad Nawaz Harrison, William T. A. Haider, Muhammad Salman Syed, Quratulain Mazhar, Sania Shoaib, Muhammad |
| description | A coordination polymer, [Cu(tmen)(succ)]
n
·4nH
2
O (1) (where succ
2-
= succinate dianion, tmen = N,N,N′,N′-tetramethylethylenediamine), was prepared by reacting CuCl
2
·2H
2
O, succinic acid (H
2
succin) and tmen, and was characterized by elemental analysis, UV-visible spectroscopy, FTIR spectroscopy, thermogravimetric (TGA) and single-crystal X-ray diffraction analyses. The copper(II) ion in 1 has a distorted cis-CuN
2
O
4
octahedral coordination environment in which the metal ion is bonded to a chelating tmen molecule and four O atoms from two bridging, asymmetrically chelating succ dianions. The bridging succ dianions link the copper(II) ions into [100] polymeric chains. In the crystal, all the H atoms of the water molecules of crystallization form O-H···O hydrogen bonds, which together with weak C-H...O hydrogen bonds results in a three-dimensional supramolecular network. The antibacterial activity of 1 was studied using the strains Bacillus spizizenii, Escherichia coli, Klebsiella pneumonia, Staphylococcus aureus, and antifungal activity was studied for Aspergillus niger. It showed significant activity against E. coli. |
| doi_str_mv | 10.1080/00958972.2020.1795147 |
| format | article |
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n
·4nH
2
O (1) (where succ
2-
= succinate dianion, tmen = N,N,N′,N′-tetramethylethylenediamine), was prepared by reacting CuCl
2
·2H
2
O, succinic acid (H
2
succin) and tmen, and was characterized by elemental analysis, UV-visible spectroscopy, FTIR spectroscopy, thermogravimetric (TGA) and single-crystal X-ray diffraction analyses. The copper(II) ion in 1 has a distorted cis-CuN
2
O
4
octahedral coordination environment in which the metal ion is bonded to a chelating tmen molecule and four O atoms from two bridging, asymmetrically chelating succ dianions. The bridging succ dianions link the copper(II) ions into [100] polymeric chains. In the crystal, all the H atoms of the water molecules of crystallization form O-H···O hydrogen bonds, which together with weak C-H...O hydrogen bonds results in a three-dimensional supramolecular network. The antibacterial activity of 1 was studied using the strains Bacillus spizizenii, Escherichia coli, Klebsiella pneumonia, Staphylococcus aureus, and antifungal activity was studied for Aspergillus niger. It showed significant activity against E. coli.</description><identifier>ISSN: 0095-8972</identifier><identifier>EISSN: 1029-0389</identifier><identifier>DOI: 10.1080/00958972.2020.1795147</identifier><language>eng</language><publisher>Abingdon: Taylor & Francis</publisher><subject>Anions ; Bonding strength ; Chelation ; Chemical bonds ; Coordination compounds ; coordination polymer ; Coordination polymers ; Copper ; Copper compounds ; Copper(II) carboxylates ; Crystal structure ; Crystallization ; Crystals ; E coli ; Fungicides ; Hydrogen bonds ; Klebsiella ; N,N,N′,N′-tetramethylethylenediamine ; Single crystals ; Spectrum analysis ; succinate ; Succinic acid ; Water chemistry</subject><ispartof>Journal of coordination chemistry, 2020-06, Vol.73 (12), p.1778-1789</ispartof><rights>2020 Informa UK Limited, trading as Taylor & Francis Group 2020</rights><rights>2020 Informa UK Limited, trading as Taylor & Francis Group</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c338t-e549733bb994cc7627f191da34c16f2d037123e88069354a6cc9b37e896d74413</citedby><cites>FETCH-LOGICAL-c338t-e549733bb994cc7627f191da34c16f2d037123e88069354a6cc9b37e896d74413</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Batool, Syeda Shahzadi</creatorcontrib><creatorcontrib>Gilani, Syeda Rubina</creatorcontrib><creatorcontrib>Zainab, Syeda Sakina</creatorcontrib><creatorcontrib>Tahir, Muhammad Nawaz</creatorcontrib><creatorcontrib>Harrison, William T. A.</creatorcontrib><creatorcontrib>Haider, Muhammad Salman</creatorcontrib><creatorcontrib>Syed, Quratulain</creatorcontrib><creatorcontrib>Mazhar, Sania</creatorcontrib><creatorcontrib>Shoaib, Muhammad</creatorcontrib><title>Synthesis, crystal structure, thermal studies and antimicrobial activity of a new chelate complex of copper(II) succinate with N,N,N′,N′-tetramethylethylenediamine</title><title>Journal of coordination chemistry</title><description>A coordination polymer, [Cu(tmen)(succ)]
n
·4nH
2
O (1) (where succ
2-
= succinate dianion, tmen = N,N,N′,N′-tetramethylethylenediamine), was prepared by reacting CuCl
2
·2H
2
O, succinic acid (H
2
succin) and tmen, and was characterized by elemental analysis, UV-visible spectroscopy, FTIR spectroscopy, thermogravimetric (TGA) and single-crystal X-ray diffraction analyses. The copper(II) ion in 1 has a distorted cis-CuN
2
O
4
octahedral coordination environment in which the metal ion is bonded to a chelating tmen molecule and four O atoms from two bridging, asymmetrically chelating succ dianions. The bridging succ dianions link the copper(II) ions into [100] polymeric chains. In the crystal, all the H atoms of the water molecules of crystallization form O-H···O hydrogen bonds, which together with weak C-H...O hydrogen bonds results in a three-dimensional supramolecular network. The antibacterial activity of 1 was studied using the strains Bacillus spizizenii, Escherichia coli, Klebsiella pneumonia, Staphylococcus aureus, and antifungal activity was studied for Aspergillus niger. It showed significant activity against E. coli.</description><subject>Anions</subject><subject>Bonding strength</subject><subject>Chelation</subject><subject>Chemical bonds</subject><subject>Coordination compounds</subject><subject>coordination polymer</subject><subject>Coordination polymers</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Copper(II) carboxylates</subject><subject>Crystal structure</subject><subject>Crystallization</subject><subject>Crystals</subject><subject>E coli</subject><subject>Fungicides</subject><subject>Hydrogen bonds</subject><subject>Klebsiella</subject><subject>N,N,N′,N′-tetramethylethylenediamine</subject><subject>Single crystals</subject><subject>Spectrum analysis</subject><subject>succinate</subject><subject>Succinic acid</subject><subject>Water chemistry</subject><issn>0095-8972</issn><issn>1029-0389</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9UU1v1DAQtRCVWFp-ApIlLiBtir8SxzdQxcdKFT0UzpbXmWhdJXawnS658W-485P4JTjdckWjmZHmvTcjzUPoJSWXlLTkLSGqbpVkl4ywMpKqpkI-QRtKmKoIb9VTtFk51Up6hp6ndEcI5ZzJDfp1u_h8gOTSFtu4pGwGnHKcbZ4jbHGB4vgwmjsHCRvflcxudDaGvSuIsdndu7zg0GODPRyxPcBgMmAbxmmAHytgwzRBfL3bvcFpttb5FT-6fMBftiX-_Pz9UKoMOZoR8mEZTsVD58zoPFygs94MCV489nP07eOHr1efq-ubT7ur99eV5bzNFdRCSc73e6WEtbJhsqeKdoYLS5uedYRLyji0LWkUr4VprFV7LqFVTSeFoPwcvTrtnWL4PkPK-i7M0ZeTmgkuhOSKsMKqT6zyhZQi9HqKbjRx0ZTo1RP9zxO9eqIfPSm6dyed830ojz2GOHQ6m2UIsY_GW5c0__-Kv5RLl14</recordid><startdate>20200617</startdate><enddate>20200617</enddate><creator>Batool, Syeda Shahzadi</creator><creator>Gilani, Syeda Rubina</creator><creator>Zainab, Syeda Sakina</creator><creator>Tahir, Muhammad Nawaz</creator><creator>Harrison, William T. A.</creator><creator>Haider, Muhammad Salman</creator><creator>Syed, Quratulain</creator><creator>Mazhar, Sania</creator><creator>Shoaib, Muhammad</creator><general>Taylor & Francis</general><general>Taylor & Francis Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20200617</creationdate><title>Synthesis, crystal structure, thermal studies and antimicrobial activity of a new chelate complex of copper(II) succinate with N,N,N′,N′-tetramethylethylenediamine</title><author>Batool, Syeda Shahzadi ; Gilani, Syeda Rubina ; Zainab, Syeda Sakina ; Tahir, Muhammad Nawaz ; Harrison, William T. A. ; Haider, Muhammad Salman ; Syed, Quratulain ; Mazhar, Sania ; Shoaib, Muhammad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c338t-e549733bb994cc7627f191da34c16f2d037123e88069354a6cc9b37e896d74413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Anions</topic><topic>Bonding strength</topic><topic>Chelation</topic><topic>Chemical bonds</topic><topic>Coordination compounds</topic><topic>coordination polymer</topic><topic>Coordination polymers</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Copper(II) carboxylates</topic><topic>Crystal structure</topic><topic>Crystallization</topic><topic>Crystals</topic><topic>E coli</topic><topic>Fungicides</topic><topic>Hydrogen bonds</topic><topic>Klebsiella</topic><topic>N,N,N′,N′-tetramethylethylenediamine</topic><topic>Single crystals</topic><topic>Spectrum analysis</topic><topic>succinate</topic><topic>Succinic acid</topic><topic>Water chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Batool, Syeda Shahzadi</creatorcontrib><creatorcontrib>Gilani, Syeda Rubina</creatorcontrib><creatorcontrib>Zainab, Syeda Sakina</creatorcontrib><creatorcontrib>Tahir, Muhammad Nawaz</creatorcontrib><creatorcontrib>Harrison, William T. A.</creatorcontrib><creatorcontrib>Haider, Muhammad Salman</creatorcontrib><creatorcontrib>Syed, Quratulain</creatorcontrib><creatorcontrib>Mazhar, Sania</creatorcontrib><creatorcontrib>Shoaib, Muhammad</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Batool, Syeda Shahzadi</au><au>Gilani, Syeda Rubina</au><au>Zainab, Syeda Sakina</au><au>Tahir, Muhammad Nawaz</au><au>Harrison, William T. A.</au><au>Haider, Muhammad Salman</au><au>Syed, Quratulain</au><au>Mazhar, Sania</au><au>Shoaib, Muhammad</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, crystal structure, thermal studies and antimicrobial activity of a new chelate complex of copper(II) succinate with N,N,N′,N′-tetramethylethylenediamine</atitle><jtitle>Journal of coordination chemistry</jtitle><date>2020-06-17</date><risdate>2020</risdate><volume>73</volume><issue>12</issue><spage>1778</spage><epage>1789</epage><pages>1778-1789</pages><issn>0095-8972</issn><eissn>1029-0389</eissn><abstract>A coordination polymer, [Cu(tmen)(succ)]
n
·4nH
2
O (1) (where succ
2-
= succinate dianion, tmen = N,N,N′,N′-tetramethylethylenediamine), was prepared by reacting CuCl
2
·2H
2
O, succinic acid (H
2
succin) and tmen, and was characterized by elemental analysis, UV-visible spectroscopy, FTIR spectroscopy, thermogravimetric (TGA) and single-crystal X-ray diffraction analyses. The copper(II) ion in 1 has a distorted cis-CuN
2
O
4
octahedral coordination environment in which the metal ion is bonded to a chelating tmen molecule and four O atoms from two bridging, asymmetrically chelating succ dianions. The bridging succ dianions link the copper(II) ions into [100] polymeric chains. In the crystal, all the H atoms of the water molecules of crystallization form O-H···O hydrogen bonds, which together with weak C-H...O hydrogen bonds results in a three-dimensional supramolecular network. The antibacterial activity of 1 was studied using the strains Bacillus spizizenii, Escherichia coli, Klebsiella pneumonia, Staphylococcus aureus, and antifungal activity was studied for Aspergillus niger. It showed significant activity against E. coli.</abstract><cop>Abingdon</cop><pub>Taylor & Francis</pub><doi>10.1080/00958972.2020.1795147</doi><tpages>12</tpages></addata></record> |
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| ispartof | Journal of coordination chemistry, 2020-06, Vol.73 (12), p.1778-1789 |
| issn | 0095-8972 1029-0389 |
| language | eng |
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| source | Taylor and Francis Science and Technology Collection |
| subjects | Anions Bonding strength Chelation Chemical bonds Coordination compounds coordination polymer Coordination polymers Copper Copper compounds Copper(II) carboxylates Crystal structure Crystallization Crystals E coli Fungicides Hydrogen bonds Klebsiella N,N,N′,N′-tetramethylethylenediamine Single crystals Spectrum analysis succinate Succinic acid Water chemistry |
| title | Synthesis, crystal structure, thermal studies and antimicrobial activity of a new chelate complex of copper(II) succinate with N,N,N′,N′-tetramethylethylenediamine |
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