Ni–Co alloy electrodeposition from the cathode powder of Ni-MH spent batteries leached with a deep eutectic solvent (reline)

• Published in: Journal of alloys and compounds 2020-07, Vol.830, p.154650, Article 154650
• Main Authors: Landa-Castro, M., Aldana-González, J., Montes de Oca-Yemha, M.G., Romero-Romo, M., Arce-Estrada, E.M., Palomar-Pardavé, M.
• Format: Article
• Language: English
• Subjects: Batteries recycling; Bimetals; Cathodes; Chlorides; Choline; Current density; Deep eutectic solvents; Electrodeposition; Ethylene glycol; Glassy carbon; Leaching; Metal hydrides; Nickel base alloys; Ni–Co alloy; Nucleation; Nuclei; Rechargeable batteries; Solvents; Substrates
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2020.154650

Choline chloride based-deep eutectic solvents (DES), namely: choline chloride (ChCl): urea (U), reline, ChCl: glycerol (G), and ChCl: ethylene glycol (EG), ethaline, were used as leaching media for the cathode powder of spent Ni-MH batteries. It is shown that the best metal extraction was obtained with the reline DES. The resulting solution was used as electrolytic bath for the electrochemical deposition of a Ni–Co alloy onto a glassy carbon electrode (GCE). A theoretical model that involves the simultaneous presence of two contributions, to the total current density, namely: three-dimensional nucleation and diffusion-controlled growth of the bimetallic phases, and the residual water reduction on the growing surfaces of the bimetallic (Ni–Co) nuclei, was implemented for the analysis of the potentiostatic current density transients. From this analysis, the potential dependence of kinetic parameters was obtained. SEM images of the GCE, after the potentiostatic electrodeposition, showed the formation of nuclei distributed all over the substrate surface. From EDX and XRD analysis it is shown that these nuclei were composed by Ni, Co and oxygen. [Display omitted] •Reline was used as leaching media of cathode powder of Ni-MH spent batteries.•Resulting liquor was used as electrolytic bath for Ni–Co alloy electrodeposition.•Ni–Co electrodeposition mechanism and kinetics onto glassy carbon was assessed.•3D nucleation of Ni–Co and water reduction occurs simultaneously.•Reline is a green alternative for metal recovery from spent batteries.