Extending the vibrational lifetime of azides with heavy atoms

The development of novel vibrational reporters (VRs), aka infrared (IR) probes, to study local environments and dynamic processes in biomolecules and materials continues to be an important area of research. Azides are important VRs because of their small size and large transition dipole strengths, h...

Full description

Saved in:
Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2020-08, Vol.22 (32), p.187-1813
Main Authors: Chalyavi, Farzaneh, Schmitz, Andrew J, Fetto, Natalie R, Tucker, Matthew J, Brewer, Scott H, Fenlon, Edward E
Format: Article
Language:English
Subjects:
Azide
Biomolecules
Dipoles
Infrared spectroscopy
Isotopic labeling
Lifetime
Nitrogen isotopes
Scaffolding
Service life assessment
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The development of novel vibrational reporters (VRs), aka infrared (IR) probes, to study local environments and dynamic processes in biomolecules and materials continues to be an important area of research. Azides are important VRs because of their small size and large transition dipole strengths, however, their relatively short vibrational lifetimes (
ISSN:1463-9076
1463-9084
DOI:10.1039/d0cp02814b