Tetrahydrofuran-based two-step solvent liquefaction process for production of lignocellulosic sugars

Large-scale production of biofuels and chemicals will require cost-effective, sustainable, and rapid deconstruction of woody biomass into its constituent sugars. Here, we introduce a novel two-step liquefaction process for producing fermentable sugars from red oak using a mixture of tetrahydrofuran...

Full description

Saved in:
Bibliographic Details
Published in:Reaction chemistry & engineering 2020-09, Vol.5 (9), p.1694-177
Main Authors: Ghosh, Arpa, Haverly, Martin R, Lindstrom, Jake K, Johnston, Patrick A, Brown, Robert C
Format: Article
Language:English
Subjects:
Biofuels
Biomass
Lignin
Lignocellulose
Liquefaction
Low temperature
Pretreatment
Recovery
Renewable resources
Saccharification
Solubilization
Solvents
Sugar
Sulfuric acid
Tetrahydrofuran
Toxicity
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Large-scale production of biofuels and chemicals will require cost-effective, sustainable, and rapid deconstruction of woody biomass into its constituent sugars. Here, we introduce a novel two-step liquefaction process for producing fermentable sugars from red oak using a mixture of tetrahydrofuran (THF), water and dilute sulfuric acid. THF promotes acid-catalyzed solubilization of lignin and hemicellulose in biomass achieving 61% lignin extraction and 64% xylose recovery in a mild pretreatment step. The pretreatment opens the structure of biomass through delignification and produces a cellulose-rich biomass, which is readily solubilized at low temperature giving 65% total sugar yields in a subsequent liquefaction process employing the same solvent mixture. This process achieves competitive sugar yields at high volumetric productivity compared to conventional saccharification methods. THF, which can be derived from renewable resources, has several benefits as solvent including ease of recovery from the sugar solution and relatively low toxicity and cost. THF-based solvent liquefaction demonstrates a new economic and sustainable approach for fractionating, saccharifying biomass with simple and efficient solvent recovery.
ISSN:2058-9883
2058-9883
DOI:10.1039/d0re00192a