Effect of visible light on the removal of trichloromethane by graphene oxide

• Published in: Diamond and related materials 2020-06, Vol.106, p.107814, Article 107814
• Main Authors: Ulucan-Altuntas, Kubra, Debik, Eyup, Ustundag, Cem Bulent, Guven, Miray Deniz, Gocen, Kubra Ayca
• Format: Article
• Language: English
• Subjects: Adsorption; Chloroform; Darkness; Degradation; Graphene; Graphene oxide; Isotherms; Nanoparticle; Photocatalytic degradation; Synthesis; Trichloromethane; Trihalomethane; Zeta potential
• ISSN: 0925-9635; 1879-0062
• DOI: 10.1016/j.diamond.2020.107814

In this experimental study, the degradation of disinfection by-products using graphene oxide was studied. Degradation of chloroform, which is the most common type of trihalomethanes in water, was investigated. Graphene oxide (GO) was synthesized by the Modified Hummers' Method. TEM images showed that the synthesized graphene oxide was exfoliated layer by layer and was very stable according to the zeta potential result. In the degradation studies; the effect of time, chloroform concentration and graphene oxide concentration were investigated both under visible light and under darkness. According to the experimental results, studies containing 100 μg/L trichloromethane and 250 mg/L GO were stabilized after 30 min and the removal of 70.6% for darkness increased to 98% under visible light. When the graphene oxide concentration is increased, it is seen that the positive effect of visible light increases from 22% to 30%. According to the isotherm and kinetic model research, it was found that the studies conducted in both conditions were appropriate to Freundlich isotherm and Pseudo second-order kinetic model. The maximum adsorption capacities based on Pseudo second-order kinetic modeling was obtained as 350 and 450 μg/g for darkness and visible light, respectively. [Display omitted] •Stabilized graphene oxide was synthesized according to Modified Hummers' method.•TCM can be removed in high efficiency at the first 5 min under visible light.•Removal efficiencies increased by 22–30% related to GO concentration under light.•Results were appropriate to Freundlich isotherm and Pseudo-second order modeling.•According to the kinetic model, adsorption capacity increased by 28.6% under light.