Novel three-dimensional TiO2-Fe3O4@polypyrrole composites with tunable microwave absorption in the 2–40 GHz frequency range

• Published in: Journal of materials science 2020-11, Vol.55 (32), p.15493-15509
• Main Authors: Liu, Fubin, Li, Cuiping, Jiang, Xiaohui, Waterhouse, Geoffrey I. N., Xing, Cuijuan, Zhang, Zhiming, Yu, Liangmin
• Format: Article
• Language: English
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Classical Mechanics; Composites & Nanocomposites; Crystallography and Scattering Methods; Electromagnetic radiation; Frequency ranges; Iron oxides; Magnetic properties; Materials Science; Microwave absorption; Microwave frequencies; Polymer Sciences; Polypyrroles; Reflection; Solid Mechanics; Thickness; Three dimensional composites; Titanium dioxide
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-020-05114-3

Enormous research effort is currently being directed toward the development of low-cost electromagnetic wave absorbing (EMWA) materials that operate at microwave frequencies. Herein, we report the successful fabrication of novel three-dimensional TiO 2 -Fe 3 O 4 @Polypyrrole (T-F-P) composites with excellent microwave absorption properties between 2 and 40 GHz. By varying the thickness of the T-F-P absorber from 1.5 to 2.5 mm, an effective absorption bandwidth (EAB, reflection loss (RL) ≤ − 10 dB) of 28.12 GHz (11.88–40 GHz) was realized. At a thickness of 2.5 mm, the minimum reflection loss (RL min ) was − 37.49 dB (13.84 GHz) in the frequency range 2–18 GHz; − 41.30 dB (25.30 GHz) in the frequency range 18–26.5 GHz and − 42.65 dB (34.1 GHz) in the frequency range 26.5–40 GHz. Multiple reflections, interfacial polarization, conductive losses and magnetic losses all contribute to the excellent EMWA properties of the T-F-P composites.