Multiphase Strengthening of Nanosized Precipitates in a Cost‐Effective Austenitic Heat‐Resistant Steel

• Published in: Steel research international 2020-09, Vol.91 (9), p.n/a
• Main Authors: Du, JiKang, Zhang, YiFan, Wang, ShaoLin, Zhou, ShuLiang, Liu, PingPing, Xie, XiShan, Geng, WenTong, Zhan, Qian
• Format: Article
• Language: English
• Subjects: atom probe tomography; Austenitic stainless steels; Carbon nitride; Chemical precipitation; Copper; Creep rupture strength; heat-resistant steels; High temperature; Mechanical properties; microstructures; Multiphase; multiphase strengthening; nanosized precipitates; Niobium; Precipitates; Strengthening; Superheaters; Thermal stability; transmission electron microscopy
• ISSN: 1611-3683; 1869-344X
• DOI: 10.1002/srin.202000122

A newly developed austenitic heat‐resistant steel Fe–22Cr–15Ni (SP2215) is aged at 700 °C for different times, which presents good mechanical properties. The stress rupture strength can be maintained at 78 MPa by extrapolating to 105 h at 700 °C. Transmission electron microscopy (TEM) analysis reveals the multiphase composites strengthening mechanism. Three types of precipitates, the coherent Cu‐rich particles, Nb‐rich carbonitrides and NbCrN phase, are found in the austenitic matrix. The fine Cu‐rich particles are the first to precipitate, most densely and homogeneously distributed, as is illustrated by atom probe tomography (APT). It is concluded that it is the multiphase nanoprecipitate strengthening and the high thermal stability of the precipitates that render the excellent mechanical properties at high temperature. With the significant advantages of high strength at 700 °C and cost‐effective, the novel austenitic heat‐resistant steel SP2215 is recommended to be a promising material for high‐efficiency superheaters/reheaters of ultra‐supercritical unit boiler at steam temperature from 620 to 650 °C. Multiphase strengthening of nano sized precipitates in SP2215 heat‐resistant steel is studied by transmission electron microscopy and atom probe tomography. The stress rupture strength is measured as 78 MPa by extrapolating to 100 000 h at 700 °C, due to the precipitation strengthening of coherent Cu‐rich particles, Nb‐rich carbonitrides, and NbCrN phase. The precipitation behavior of those particles is studied.