Corrosion inhibition of aluminum type 6061 Al-15 vol. pct. SiC(p) composite in 0.5-M sodium hydroxide solution by 4-amino-5-phenyl-4H-1,2,4-triazole-3-thiol

• Published in: Anti-corrosion methods and materials 2014-01, Vol.61 (4), p.241-249
• Main Authors: Kumari P.D, Reena, Nayak, Jagannath, Nityananda Shetty, A
• Format: Article
• Language: English
• Subjects: Adsorption; Alloys; Aluminium; Aluminum; Aluminum base alloys; Caustic soda; Composite materials; Corrosion; Corrosion inhibitors; Corrosion potential; Corrosion prevention; Corrosion resistance; Efficiency; Electrochemical impedance spectroscopy; Electrochemistry; Electrodes; Electron microscopy; Engineering; Hydroxides; Inhibition; Inhibitors; Mechanical engineering; Metal surfaces; Metals; Morphology; Parameters; Sodium; Sodium hydroxide; Spectroscopic techniques; Spectrum analysis; Studies; Surface chemistry; Temperature; Triazoles
• ISSN: 0003-5599; 1758-4221
• DOI: 10.1108/ACMM-12-2012-1228

Purpose – The purpose of this paper is to report the studies on the corrosion inhibition property of 4-amino-5-phenyl-4H-1,2,4-triazole-3-thiol (APTT) for the corrosion of 6061 Al-15 vol. pct. SiC(p) composite. Design/methodology/approach – The corrosion behavior of 6061 Al-15 vol. pct. SiC(p) composite was studied at different temperatures in 0.5-M sodium hydroxide (NaOH) solution in the presence of APTT by potentiodynamic polarization (PDP) and electrochemical impedance spectroscopic techniques. The effect of inhibitor concentration and temperature on the inhibitor effect of APTT was studied. The surface morphology of the metal surface was investigated by scanning electron microscopy. The activation parameters for the corrosion of the composite and base alloy, as well as the thermodynamic parameters for the adsorption of APTT on the composite and alloy surfaces, were calculated. Findings – The inhibition efficiency of APTT increases with the increase in the concentration of the inhibitor and decreases with the increase in temperature. The adsorption of APTT on the composite was found to be through physisorption, obeying Langmuir’s adsorption isotherm. APTT acts as a mixed inhibitor with predominant cathodic action on the composite. Practical implications – APTT can be used as an inhibitor for the corrosion of 6061 Al-15 vol. pct. SiC(p) composite in the NaOH medium. Originality/value – This paper provides information regarding the corrosion inhibition property of APTT on 6061 Al-15 vol. pct. SiC(p) composite. An attempt was made to explain the mechanism of the inhibition action by APTT.