Preparation and characterization of SrZrO3–La2Ce2O7 composite ceramics as a thermal barrier coating material

• Published in: Materials chemistry and physics 2020-06, Vol.247, p.122904, Article 122904
• Main Authors: Liu, Ying, Bai, Yu, Li, Enbo, Qi, Yingwei, Liu, Caiwen, Dong, Hongying, Jia, Ruiling, Ma, Wen
• Format: Article
• Language: English
• Subjects: Ceramic coatings; Ceramics; Chemical coprecipitation; Composite ceramics; Heat treatment; Loose powder sintering; Microhardness; Phase stability; Phase transitions; Room temperature; Stability analysis; Strontium zirconates; Thermal analysis; Thermal barrier coating; Thermal barrier coatings; Thermal conductivity; Thermal expansion; Yttria-stabilized zirconia; Yttrium oxide; Zirconium dioxide
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2020.122904

The (1-x)SrZrO3-xLa2Ce2O7(x = 0, SZ; x = 0.3, S7L3; x = 0.5, S5L5; x = 0.7, S3L7; x = 1, LC) composite powders were synthesized by a coprecipitation-calcination method. The composite bulks were fabricated by pressureless sintering at 1600 °C for 6 h. The X-ray diffraction (XRD) results indicated that the SZ-LC composite powders and bulks were comprised of the SZ and/or LC phase. The S7L3 and S5L5 bulks showed higher microhardness both in the as-sintered state and after heat-treatment at 1450 °C for different times. Their thermal expansion coefficients (TECs) revealed a positive effect on the phase transitions of the SZ-LC bulks. The composite bulks showed good phase stability from room-temperature to 1400 °C, determined by thermal analysis apparatus (DSC) and TEC analyses. The S5L5 bulk had very low thermal conductivity (0.97 W m−1 K−1, 1200 °C) compared with SZ and 8 wt% Y2O3-stabilized ZrO2 (8YSZ) over the same temperature range. Therefore, the S5L5 composite ceramics is considered to be a potential material for thermal barrier coating applications at higher temperatures than 8YSZ. •The SrZrO3–La2Ce2O7 (SZ-LC) bulks prepared by pressureless sintering method.•The fracture toughnesses of the SZ-LC composite ceramics are significantly higher than those of SZ and LC.•The TEC of the S5L5 bulk is 11.3 × 10−6 K−1 (1200 °C) and the thermal conductivity is 0.97 W m−1 K−1 at 1200°C.•The thermal properties of SZ-LC composite ceramics are excellent than single phase.