Characteristics and photocatalytic activity of highly c-axis-oriented ZnO thin films

• Published in: Journal of sol-gel science and technology 2020-10, Vol.96 (1), p.226-235
• Main Authors: Aryanto, Didik, Hastuti, Erna, Taspika, Melda, Anam, Khoirul, Isnaeni, Isnaeni, Widayatno, Wahyu B., Wismogroho, Agus S., Marwoto, Putut, Nuryadin, Bebeh W., Noviyanto, Alfian, Sugianto, Sugianto
• Format: Article
• Language: English
• Subjects: Annealing; Catalytic activity; Ceramics; Chemistry and Materials Science; Composites; Crystal structure; Crystallinity; Crystallography; Doppler effect; Emission; Glass; Glass substrates; Inorganic Chemistry; Materials Science; Morphology; Nanotechnology; Natural Materials; Optical and Electronic Materials; Optical properties; Orientation; Original Paper: Sol–gel and hybrid materials for catalytic; Photocatalysis; photoelectrochemical and sensor applications; Photoluminescence; Red shift; Rhodamine; Room temperature; Sol-gel processes; Spin coating; Thin films; Transmittance; Wurtzite; Zinc oxide
• ISSN: 0928-0707; 1573-4846
• DOI: 10.1007/s10971-020-05361-5

ZnO thin films are deposited on glass substrate using sol–gel spin coating methods with various annealing temperatures. The structural, morphological, and optical properties are studied by XRD, FE-SEM, UV–Vis, and photoluminescence spectrophotometer. The photocatalytic activity was assessed by examining the decomposition of Rhodamine-B (Rh-B) dye under UV illumination. The result shows that the ZnO films have a hexagonal wurtzite structure with highly preferred c -axis orientation. The (101) crystallographic plane appears at higher annealing temperatures. The transmittance of ZnO films is more than 80%, with a slight red shift in absorption and decrease in the optical band gaps as the annealing temperature increases to some extent. The photoluminescence spectra of the ZnO films at room temperature demonstrated the ultra-violet (UV) emission with a peak emission at 410 nm (3.03 eV). According to the photocatalytic activity examination, the presence of (101) plane in the c -axis oriented ZnO films enhances the photocatalytic performance by a factor of 5. The result revealed that ZnO films with multi-orientation structure possess better photocatalytic performance than that of the single-orientation ones. In particular, the photocatalytic performance is highly contributed by the polar crystal plane and slightly improved by the crystallinity and surface morphology. Highlights ZnO films with highly preferred c -axis orientation were prepared using sol–gel spin coating technique. The ZnO films have a transmittance more than 80% with an ultra-violet (UV) emission peak at 3.03 eV. The polar crystal plane gives more significant contribution on the photocatalytic performance than that of the crystallinity and surface morphology.