Preparation of uniform and highly dispersed magnetic copper ferrite sub-micron sized particles regulated by short-chain surfactant with catechol structure: Dual-functional materials for supercapacitor and dye degradation

In this work, a dual-functional materials which can be used for both supercapacitors and dye degradation was prepared through simple one-pot solvothermal method using an environmentally friendly short-chain surfactant with special catechol structure. By adjusting the concentrations of the surfactant...

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Bibliographic Details
Published in:Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2020-08, Vol.870, p.114199, Article 114199
Main Authors: Zhang, Xiai, Liu, Haitao, Liang, Chen, Ren, Fujun, Zhao, Jinyuan, Wang, Tong, Zhong, Rui, Zhang, Deyi, Zhu, Hao
Format: Article
Language:English
Subjects:
Bifunctional
Capacitance
Catechol
Chains
Contaminants
Copper ferrite
Crystal structure
Current density
Degradation
Dopamine
Dyes
Functional materials
Malachite green
Spherical copper ferrite
Supercapacitors
Surfactants
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Summary:In this work, a dual-functional materials which can be used for both supercapacitors and dye degradation was prepared through simple one-pot solvothermal method using an environmentally friendly short-chain surfactant with special catechol structure. By adjusting the concentrations of the surfactant added, the crystal structures of the samples could be controlled during the solvothermal process. The sizes of spherical copper ferrite sub-micron sized particles were controlled through the interactions between the metal ion and the catechol-like structure of the ligand. Further investigation of the performance indicated that the magnetic copper ferrite particles which were prepared with 1 mmol·L−1 of the surfactant displayed specific capacitance (up to 960.73 F·g−1) at a current density of 1A·g−1. And after cycling 1000 times at a current density of 10 A·g−1, the initial capacitance retention rate is 57.1%. In addition, the electrode was used to activate peroxymonosulfate (PMS) to achieve rapid and efficient degradation of Malachite green (MG) contaminants and the degradation efficiency was as high as 96% within 20 min. [Display omitted] •Natural short-chain surfactants (DA)•Highly dispersed magnetic Spherical Copper Ferrite•Bifunctional catalyst•Supercapacitors•Dye degradation
ISSN:1572-6657
1873-2569
DOI:10.1016/j.jelechem.2020.114199