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A series of heterobimetallic Ni(II)–Ln(III) (Ln = La, Ce, Pr and Nd) coordination polymers derived from 3-EtOsalamo and dicarboxylates: syntheses, crystal structures and fluorescence properties
Four coordination polymers ∞ 2 [Ni(DMF)(L)Ln(bdc) 1.5 ] (Ln = La ( 1 ) and Nd ( 4 )) and ∞ 2 [Ni 2 (DMF) 2 (L) 2 Ln 2 (bdc) 3 ]·CH 3 OH (Ln = Ce ( 2 ) and Pr ( 3 )) were derived from a symmetrical salamo-based ligand (H 2 L) with Ni(OAc) 2 ·4H 2 O, Ln(NO 3 ) 3 ·6H 2 O (Ln = La, Ce, Pr and Nd), a...
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| Published in: | Transition metal chemistry (Weinheim) 2020-10, Vol.45 (7), p.485-492 |
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| Main Authors: | , , , , |
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| cited_by | cdi_FETCH-LOGICAL-c319t-8ee96208066ebd95bfa53fba0f947e77e3a74211efe38abc8428fa63893e9483 |
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| cites | cdi_FETCH-LOGICAL-c319t-8ee96208066ebd95bfa53fba0f947e77e3a74211efe38abc8428fa63893e9483 |
| container_end_page | 492 |
| container_issue | 7 |
| container_start_page | 485 |
| container_title | Transition metal chemistry (Weinheim) |
| container_volume | 45 |
| creator | Zhang, Yu Li, Ya-Juan Guo, Shuang-Zhu Fu, Tao Zhao, Li |
| description | Four coordination polymers
∞
2
[Ni(DMF)(L)Ln(bdc)
1.5
] (Ln
=
La (
1
) and Nd (
4
)) and
∞
2
[Ni
2
(DMF)
2
(L)
2
Ln
2
(bdc)
3
]·CH
3
OH (Ln
=
Ce (
2
) and Pr (
3
)) were derived from a symmetrical salamo-based ligand (H
2
L) with Ni(OAc)
2
·4H
2
O, Ln(NO
3
)
3
·6H
2
O (Ln = La, Ce, Pr and Nd), and H
2
bdc (terephthalic acid). Coordination polymers
1
–
4
were synthesized and characterized by elemental analyses, X-ray single crystal diffraction, infrared spectroscopy and ultraviolet–visible absorption spectroscopy. Coordination polymers
1
–
4
have similar structures exhibiting two-dimensional coordination polymers with brick wall in which [Ni(DMF)(L)Ln] units were linked by exodentate (bdc)
2−
linker. In each unit, Ni(II) atoms adopted a slightly distorted octahedral geometry, the Ln(III) atoms were nine-coordinated, and the coordination polyhedron was a distorted tricapped trigonal prism. The crystal structure and supramolecular features were discussed in detail. At the same time, the fluorescent properties of coordination polymers
1
–
4
were also investigated. |
| doi_str_mv | 10.1007/s11243-020-00400-0 |
| format | article |
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∞
2
[Ni(DMF)(L)Ln(bdc)
1.5
] (Ln
=
La (
1
) and Nd (
4
)) and
∞
2
[Ni
2
(DMF)
2
(L)
2
Ln
2
(bdc)
3
]·CH
3
OH (Ln
=
Ce (
2
) and Pr (
3
)) were derived from a symmetrical salamo-based ligand (H
2
L) with Ni(OAc)
2
·4H
2
O, Ln(NO
3
)
3
·6H
2
O (Ln = La, Ce, Pr and Nd), and H
2
bdc (terephthalic acid). Coordination polymers
1
–
4
were synthesized and characterized by elemental analyses, X-ray single crystal diffraction, infrared spectroscopy and ultraviolet–visible absorption spectroscopy. Coordination polymers
1
–
4
have similar structures exhibiting two-dimensional coordination polymers with brick wall in which [Ni(DMF)(L)Ln] units were linked by exodentate (bdc)
2−
linker. In each unit, Ni(II) atoms adopted a slightly distorted octahedral geometry, the Ln(III) atoms were nine-coordinated, and the coordination polyhedron was a distorted tricapped trigonal prism. The crystal structure and supramolecular features were discussed in detail. At the same time, the fluorescent properties of coordination polymers
1
–
4
were also investigated.</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-020-00400-0</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Catalysis ; Cerium ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Crystal structure ; Crystals ; Fluorescence ; Infrared analysis ; Inorganic Chemistry ; Lanthanum ; Organometallic Chemistry ; Physical Chemistry ; Polymers ; Praseodymium ; Single crystals ; Spectrum analysis ; Terephthalic acid</subject><ispartof>Transition metal chemistry (Weinheim), 2020-10, Vol.45 (7), p.485-492</ispartof><rights>Springer Nature Switzerland AG 2020</rights><rights>Springer Nature Switzerland AG 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-8ee96208066ebd95bfa53fba0f947e77e3a74211efe38abc8428fa63893e9483</citedby><cites>FETCH-LOGICAL-c319t-8ee96208066ebd95bfa53fba0f947e77e3a74211efe38abc8428fa63893e9483</cites><orcidid>0000-0003-3922-213X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhang, Yu</creatorcontrib><creatorcontrib>Li, Ya-Juan</creatorcontrib><creatorcontrib>Guo, Shuang-Zhu</creatorcontrib><creatorcontrib>Fu, Tao</creatorcontrib><creatorcontrib>Zhao, Li</creatorcontrib><title>A series of heterobimetallic Ni(II)–Ln(III) (Ln = La, Ce, Pr and Nd) coordination polymers derived from 3-EtOsalamo and dicarboxylates: syntheses, crystal structures and fluorescence properties</title><title>Transition metal chemistry (Weinheim)</title><addtitle>Transit Met Chem</addtitle><description>Four coordination polymers
∞
2
[Ni(DMF)(L)Ln(bdc)
1.5
] (Ln
=
La (
1
) and Nd (
4
)) and
∞
2
[Ni
2
(DMF)
2
(L)
2
Ln
2
(bdc)
3
]·CH
3
OH (Ln
=
Ce (
2
) and Pr (
3
)) were derived from a symmetrical salamo-based ligand (H
2
L) with Ni(OAc)
2
·4H
2
O, Ln(NO
3
)
3
·6H
2
O (Ln = La, Ce, Pr and Nd), and H
2
bdc (terephthalic acid). Coordination polymers
1
–
4
were synthesized and characterized by elemental analyses, X-ray single crystal diffraction, infrared spectroscopy and ultraviolet–visible absorption spectroscopy. Coordination polymers
1
–
4
have similar structures exhibiting two-dimensional coordination polymers with brick wall in which [Ni(DMF)(L)Ln] units were linked by exodentate (bdc)
2−
linker. In each unit, Ni(II) atoms adopted a slightly distorted octahedral geometry, the Ln(III) atoms were nine-coordinated, and the coordination polyhedron was a distorted tricapped trigonal prism. The crystal structure and supramolecular features were discussed in detail. At the same time, the fluorescent properties of coordination polymers
1
–
4
were also investigated.</description><subject>Catalysis</subject><subject>Cerium</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Fluorescence</subject><subject>Infrared analysis</subject><subject>Inorganic Chemistry</subject><subject>Lanthanum</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Praseodymium</subject><subject>Single crystals</subject><subject>Spectrum analysis</subject><subject>Terephthalic acid</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kb1uFDEUhS0EEkvgBags0WSlHXJtzy8SRbQKsNIooUhBZ3k812SiGXuxPRHTpaXmoXiPPEmcbKR0FLZvcb5zj3wIec_gIwOoTgJjPBcZcMgAckj3C7JiRcWzBtiPl2QFIocs53XxmrwJ4RoACl7lK_LvlAb0AwbqDL3CiN51w4RRjeOg6flwvNut727_tjYNuzU9bu3d7Z_P6bRqQ7e4od89Vban5_2aaud8P1gVB2fp3o3LhD7QPtnfYE-NdxMV2Vm8CGpUk3vE-kEr37nfy6gihk80LDZeYcCwodovIcWgIfpZx9mniA-EGWeXZo1WI917t0cfU_y35JVRY8B3T-8Rufxydrn9lrUXX3fb0zbTgjUxqxGbkkMNZYld3xSdUYUwnQLT5BVWFQpV5ZwxNChq1ek6fZlRpagbgU1eiyPy4WCbNv-aMUR57WZv00bJ8wIEg7JiScUPKu1dCB6N3PthUn6RDORDX_LQl0x9yce-JCRIHKCQxPYn-mfr_1D3sk2dNA</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Zhang, Yu</creator><creator>Li, Ya-Juan</creator><creator>Guo, Shuang-Zhu</creator><creator>Fu, Tao</creator><creator>Zhao, Li</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-3922-213X</orcidid></search><sort><creationdate>20201001</creationdate><title>A series of heterobimetallic Ni(II)–Ln(III) (Ln = La, Ce, Pr and Nd) coordination polymers derived from 3-EtOsalamo and dicarboxylates: syntheses, crystal structures and fluorescence properties</title><author>Zhang, Yu ; Li, Ya-Juan ; Guo, Shuang-Zhu ; Fu, Tao ; Zhao, Li</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-8ee96208066ebd95bfa53fba0f947e77e3a74211efe38abc8428fa63893e9483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Catalysis</topic><topic>Cerium</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Fluorescence</topic><topic>Infrared analysis</topic><topic>Inorganic Chemistry</topic><topic>Lanthanum</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Polymers</topic><topic>Praseodymium</topic><topic>Single crystals</topic><topic>Spectrum analysis</topic><topic>Terephthalic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yu</creatorcontrib><creatorcontrib>Li, Ya-Juan</creatorcontrib><creatorcontrib>Guo, Shuang-Zhu</creatorcontrib><creatorcontrib>Fu, Tao</creatorcontrib><creatorcontrib>Zhao, Li</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yu</au><au>Li, Ya-Juan</au><au>Guo, Shuang-Zhu</au><au>Fu, Tao</au><au>Zhao, Li</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A series of heterobimetallic Ni(II)–Ln(III) (Ln = La, Ce, Pr and Nd) coordination polymers derived from 3-EtOsalamo and dicarboxylates: syntheses, crystal structures and fluorescence properties</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><stitle>Transit Met Chem</stitle><date>2020-10-01</date><risdate>2020</risdate><volume>45</volume><issue>7</issue><spage>485</spage><epage>492</epage><pages>485-492</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>Four coordination polymers
∞
2
[Ni(DMF)(L)Ln(bdc)
1.5
] (Ln
=
La (
1
) and Nd (
4
)) and
∞
2
[Ni
2
(DMF)
2
(L)
2
Ln
2
(bdc)
3
]·CH
3
OH (Ln
=
Ce (
2
) and Pr (
3
)) were derived from a symmetrical salamo-based ligand (H
2
L) with Ni(OAc)
2
·4H
2
O, Ln(NO
3
)
3
·6H
2
O (Ln = La, Ce, Pr and Nd), and H
2
bdc (terephthalic acid). Coordination polymers
1
–
4
were synthesized and characterized by elemental analyses, X-ray single crystal diffraction, infrared spectroscopy and ultraviolet–visible absorption spectroscopy. Coordination polymers
1
–
4
have similar structures exhibiting two-dimensional coordination polymers with brick wall in which [Ni(DMF)(L)Ln] units were linked by exodentate (bdc)
2−
linker. In each unit, Ni(II) atoms adopted a slightly distorted octahedral geometry, the Ln(III) atoms were nine-coordinated, and the coordination polyhedron was a distorted tricapped trigonal prism. The crystal structure and supramolecular features were discussed in detail. At the same time, the fluorescent properties of coordination polymers
1
–
4
were also investigated.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11243-020-00400-0</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-3922-213X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0340-4285 |
| ispartof | Transition metal chemistry (Weinheim), 2020-10, Vol.45 (7), p.485-492 |
| issn | 0340-4285 1572-901X |
| language | eng |
| recordid | cdi_proquest_journals_2450310671 |
| source | Springer Nature |
| subjects | Catalysis Cerium Chemistry Chemistry and Materials Science Coordination polymers Crystal structure Crystals Fluorescence Infrared analysis Inorganic Chemistry Lanthanum Organometallic Chemistry Physical Chemistry Polymers Praseodymium Single crystals Spectrum analysis Terephthalic acid |
| title | A series of heterobimetallic Ni(II)–Ln(III) (Ln = La, Ce, Pr and Nd) coordination polymers derived from 3-EtOsalamo and dicarboxylates: syntheses, crystal structures and fluorescence properties |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T10%3A32%3A45IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20series%20of%20heterobimetallic%20Ni(II)%E2%80%93Ln(III)%20(Ln%E2%80%89=%E2%80%89La,%20Ce,%20Pr%20and%20Nd)%20coordination%20polymers%20derived%20from%203-EtOsalamo%20and%20dicarboxylates:%20syntheses,%20crystal%20structures%20and%20fluorescence%20properties&rft.jtitle=Transition%20metal%20chemistry%20(Weinheim)&rft.au=Zhang,%20Yu&rft.date=2020-10-01&rft.volume=45&rft.issue=7&rft.spage=485&rft.epage=492&rft.pages=485-492&rft.issn=0340-4285&rft.eissn=1572-901X&rft_id=info:doi/10.1007/s11243-020-00400-0&rft_dat=%3Cproquest_cross%3E2450310671%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c319t-8ee96208066ebd95bfa53fba0f947e77e3a74211efe38abc8428fa63893e9483%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2450310671&rft_id=info:pmid/&rfr_iscdi=true |