A new supramolecular heterosynthon [C-I O&z.dbd;C(carboxylate)] at work: engineering copper acetate cocrystals

A carboxylate iodine supramolecular heterosynthon can be reliably applied in cocrystal engineering, using metal carboxylates as building blocks. Analysis of the energy framework of the exemplary paddlewheel crystal [Cu(OAc) 2 MeOH] 2 indicates a robust 1D chain and even 2D layer long-range synthon m...

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Bibliographic Details
Published in:CrystEngComm 2020-10, Vol.22 (4), p.6661-6673
Main Authors: Torubaev, Yury V, Skabitsky, Ivan V
Format: Article
Language:English
Subjects:
Acetic acid
Bonding
Carboxylates
Copper
Copper acetate
Crystallography
Crystals
Dimers
Hydrogen bonds
Iodine
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Summary:A carboxylate iodine supramolecular heterosynthon can be reliably applied in cocrystal engineering, using metal carboxylates as building blocks. Analysis of the energy framework of the exemplary paddlewheel crystal [Cu(OAc) 2 MeOH] 2 indicates a robust 1D chain and even 2D layer long-range synthon modules, which can be intactly transferred into cocrystals. However, this approach allows the identification of a "weak link" - i.e. layers where the C-H O&z.dbd;C hydrogen bonds between ([Cu(OAc) 2 (MeOH)] 2 ) n polymeric chains will be subject to substitution by I O&z.dbd;C halogen bonds during interaction with halogen bond donor co-formers. In contrast to the O-H O&z.dbd;C/C-H O&z.dbd;C catemeric crystals of pure acetic acid, the crystal design exercise based on the I O&z.dbd;C(carboxyl) supramolecular synthon afforded a 1 : 1 cocrystal of 1,4-C 6 F 4 I 2 and CH 3 COOH, where the discrete centrosymmetric dimers of acetic acid are stabilized by I O&z.dbd;C(carboxyl) halogen bonds. Carboxylate-iodine supramolecular heterosynthons in combination with energy frameworks can be reliably applied in engineering hybrid metal-carboxylate cocrystals.
ISSN:1466-8033
1466-8033
DOI:10.1039/d0ce01093f