Electron-stimulated desorption from molecular ices in the sub-keV regime

Electron-stimulated desorption (ESD) of cryosorbed molecules on surfaces is a process of relevance to fields as varied as vacuum dynamics in accelerators and astrochemistry. While desorption from such molecular systems induced by keV electrons and fast ions has been extensively studied, the sub-keV...

Full description

Saved in:
Bibliographic Details
Published in:arXiv.org 2020-10
Main Authors: Dupuy, Rémi, Haubner, Michal, Henrist, Bernard, Fillion, Jean-Hugues, Baglin, Vincent
Format: Article
Language:English
Subjects:
Accelerators
Astrochemistry
Carbon monoxide
Cryogenic temperature
Desorption
Electron energy
Species diffusion
Stopping power
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Electron-stimulated desorption (ESD) of cryosorbed molecules on surfaces is a process of relevance to fields as varied as vacuum dynamics in accelerators and astrochemistry. While desorption from such molecular systems induced by keV electrons and fast ions has been extensively studied, the sub-keV electron regime is comparatively little known. We measured and quantified electron-stimulated desorption from molecular ice systems (layers of N\(_2\), CO, CO\(_2\), Ar and H\(_2\)O/D\(_2\)O condensed at cryogenic temperatures) in the 150-2000 eV electron energy range. In this regime stopping power is no longer sufficient to explain the electron energy dependence of ESD yields. We introduce the notion of desorption-relevant depth, which characterizes the transition between two energy deposition regimes near the surface. We then apply this notion to the different systems, showing how ESD in the sub-keV regime can for example reveal the differences in species diffusion in crystalline and porous amorphous CO\(_2\) ices.
ISSN:2331-8422
DOI:10.48550/arxiv.2010.09538