Increasing dimethyl ether production from biomass-derived syngas via sorption enhanced dimethyl ether synthesis

• Published in: Sustainable energy & fuels 2020-11, Vol.4 (11), p.5674-5681
• Main Authors: Liuzzi, Dalia, Peinado, Cristina, Peña, Miguel A., van Kampen, Jasper, Boon, Jurriaan, Rojas, Sergio
• Format: Article
• Language: English
• Subjects: Aluminum oxide; Biofuels; Biomass; Carbon dioxide; Catalysts; Deactivation; Dehydration; Dimethyl ether; Gallium; Gallium oxides; Methanol; Sorbents; Sorption; Synthesis gas; Transitional aluminas; Zeolites; Zinc oxide; Zirconium; Zirconium oxides
• ISSN: 2398-4902; 2398-4902
• DOI: 10.1039/D0SE01172J

The direct synthesis of dimethyl ether (DME) from biomass-derived syngas is a topic of great interest in the field of biofuels. The process takes place in one reactor combining two catalytic functions, Cu/ZnO/Al 2 O 3 (CZA) for the synthesis of methanol and an acid catalyst (typically γ-Al 2 O 3 ) for methanol dehydration to DME. However, the catalytic performance of those catalysts is negatively affected by the high CO 2 /CO ratio in the bio-syngas, resulting in low methanol and DME production rates. In this work, we show that promoters such as zirconium and gallium oxides increase the CO fraction in the syngas. However, the production of H 2 O is also increased, leading to the deactivation of both CZA and γ-Al 2 O 3 . The addition of a water sorbent (zeolite 3A) in the reaction medium alleviates the detrimental effect of H 2 O in the direct synthesis of DME from CO 2 -rich syngas. Thus, DME production over the CZA/γ-Al 2 O 3 catalytic bed increases from ca. 8.7% to 70% when a zeolite 3A is placed in the reaction medium. In fact, carbon conversions higher than conventional equilibrium conversions are achieved. This work demonstrates that the sorption enhanced synthesis of DME is a suitable strategy to increase DME production from biomass-derived syngas.