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Nickel nanocrystal/nitrogen-doped carbon composites as efficient and carbon monoxide-resistant electrocatalysts for methanol oxidation reactions
High-performance electrocatalysts for the methanol oxidation reaction (MOR) are the key to advance the application of direct methanol fuel cells. Pt-Based electrocatalysts for the MOR are limited due to their high cost, low stability and poor resistance to carbon monoxide (CO) poisoning. The develop...
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Published in: | Nanoscale 2020-11, Vol.12 (42), p.21687-21694 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | High-performance electrocatalysts for the methanol oxidation reaction (MOR) are the key to advance the application of direct methanol fuel cells. Pt-Based electrocatalysts for the MOR are limited due to their high cost, low stability and poor resistance to carbon monoxide (CO) poisoning. The development of non-noble metal-based electrocatalysts for the MOR with high activity and good stability is desired, but it remains a challenge. Herein, we report a simple strategy to prepare nickel nanocrystals embedded in a nitrogen-doped carbon matrix (Ni/N-C composite) by pyrolysis of Ni-coordinated polyaniline-poly(vinyl alcohol) hydrogels. These
in situ
generated Ni nanocrystals serve as active electrocatalysts for the MOR, while the nitrogen-doped carbon matrix serves as a conductive support to facilitate electron transfer and also to protect the active Ni nanocrystals. The optimal Ni/N-C@500 electrocatalyst shows a high MOR activity of 147 mA cm
−2
at 1.66 V
vs
. the RHE in alkaline methanol solution, which is outstanding among Ni-based MOR electrocatalysts. Ni/N-C@500 also shows better stability than the Pt/C catalyst in the long-term MOR test at high current densities. Upon CO poisoning, Ni/N-C@500 retains 85% of its MOR activity, far exceeding the performance of the Pt/C catalyst (61% retention). Owing to its facile synthesis, outstanding activity and high stability, the Ni/N-C@500 composite is promising as a low-cost, efficient and CO-resistant electrocatalyst for the MOR.
Owing to its facile synthesis, outstanding activity and high stability, Ni/N-C@500 composite is promising as a low-cost, efficient and CO-resistant electrocatalyst for methanol oxidation reaction (MOR). |
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ISSN: | 2040-3364 2040-3372 |
DOI: | 10.1039/d0nr04822d |