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Understanding the structural properties of p -xylylenebis(triphenylphosphonium) cation under different pH and anion conditions
The organisation of the p -xylylenebis(triphenylphosphonium) dication in the solid state, in crystals formed under a variety of conditions, at different pH values and in the presence of THF and other potential building moieties including p -sulfonatocalix[4]arene, 1-methyl-3-butylimidazolium and aqu...
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Published in: | CrystEngComm 2020-11, Vol.22 (44), p.7704-7715 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The organisation of the
p
-xylylenebis(triphenylphosphonium) dication in the solid state, in crystals formed under a variety of conditions, at different pH values and in the presence of THF and other potential building moieties including
p
-sulfonatocalix[4]arene, 1-methyl-3-butylimidazolium and aquated gadolinium(
iii
) has been investigated using single crystal X-ray diffraction studies. Striking changes in the dication conformations (
cis
- and
trans
-) that contribute to the different crystal packings of the dication (two-dimensional layerings and three-dimensional scaffoldings) have been established for five different compounds. The interplay and the self-assembled arrays of the dication with other incorporated components and the overall non-covalent interactions have been quantified using Hirshfeld surface analyses. |
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ISSN: | 1466-8033 1466-8033 |
DOI: | 10.1039/D0CE01274B |