Application of Carbon Microsphere Loaded with Magnetite Nanoparticles for the Removal of a Cationic Azo Dye: Efficiency and Mechanism

AbstractMethylene blue (MB), a cationic azo dye, is harmful to the environment and human health. In this study, carbon microspheres (CMS)@magnetite was prepared to remove MB. The performance of CMS@magnetite on MB removal and adsorption mechanisms was studied. Transmission electron microscopy, Fouri...

Full description

Saved in:
Bibliographic Details
Published in:Journal of environmental engineering (New York, N.Y.) N.Y.), 2021-02, Vol.147 (2)
Main Authors: Yu, Peijing, Fu, Fenglian
Format: Article
Language:English
Subjects:
Adsorption
Azo dyes
Carbon
Cations
Efficiency
Electrostatic properties
Fourier transforms
Infrared spectroscopy
Magnetic measurement
Magnetite
Methylene blue
Microspheres
Nanoparticles
Photoelectron spectroscopy
Photoelectrons
Recycling
Spectrum analysis
Technical Papers
Transmission electron microscopy
Wastewater
Wastewater treatment
X ray photoelectron spectroscopy
X-ray diffraction
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a374t-b5e9b56ab1f35ff48a1be1368bc0f6c35076e025dd23ffc318b0d3ba0256a1293
cites cdi_FETCH-LOGICAL-a374t-b5e9b56ab1f35ff48a1be1368bc0f6c35076e025dd23ffc318b0d3ba0256a1293
container_end_page
container_issue 2
container_start_page
container_title Journal of environmental engineering (New York, N.Y.)
container_volume 147
creator Yu, Peijing
Fu, Fenglian
description AbstractMethylene blue (MB), a cationic azo dye, is harmful to the environment and human health. In this study, carbon microspheres (CMS)@magnetite was prepared to remove MB. The performance of CMS@magnetite on MB removal and adsorption mechanisms was studied. Transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller, X-ray diffraction, and vibrating-sample magnetometry were used to characterize the CMS@magnetite before and after adsorption with MB. The effects of different dosages and initial pH values on MB removal by CMS@magnetite were studied through batch experiments. Results reflected that CMS@magnetite had high removal efficiency on MB. In addition, adsorption isotherms, kinetics, and thermodynamics models were also studied. MB adsorption behavior was better described by the Langmuir model. The experimental data of MB adsorption by CMS@magnetite had a higher fitting degree with a pseudo-second-order kinetic model. In addition, reuse experiments were studied, which showed the advantage of good recycling ability of CMS@magnetite. MB was removed by CMS@magnetite through electrostatic adsorption and π-π interaction. Because of high removal efficiency, easy separation, and high performance of recycling, CMS@magnetite can be potentially used to remove MB wastewater.
doi_str_mv 10.1061/(ASCE)EE.1943-7870.0001839
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2462343182</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2462343182</sourcerecordid><originalsourceid>FETCH-LOGICAL-a374t-b5e9b56ab1f35ff48a1be1368bc0f6c35076e025dd23ffc318b0d3ba0256a1293</originalsourceid><addsrcrecordid>eNp1kLFu2zAQhokiBeK6eQeiWdpBDilKlOTNcNS0gN0AbTITJ-oY0bBFlZQTuHveOxLspFOmOxz-7z_gI-QLZzPOJL_6uvizLL-V5YwXiYiyPGMzxhjPRfGBTN5uZ2TCMiGiQmTxOfkUwmbIJLLIJuR50XVbq6G3rqXO0CX4atjWVnsXugY90pWDGmv6ZPuGruGhxd72SH9B6zrwvdVbDNQ4T_sG6W_cuUfYjk0wdI2tVtPFP0evDzinpTFWW2z1gUJb0zXqBlobdp_JRwPbgBenOSX338u75Y9odXvzc7lYRSCypI-qFIsqlVBxI1Jjkhx4hVzIvNLMSC1SlklkcVrXsTBGC55XrBYVDCcJPC7ElFweezvv_u4x9Grj9r4dXqo4kbFIBiQeUvNjanQQPBrVebsDf1CcqVG7UqN2VZZqVKxGxeqkfYDlEYag8X_9K_k--AINdYfU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2462343182</pqid></control><display><type>article</type><title>Application of Carbon Microsphere Loaded with Magnetite Nanoparticles for the Removal of a Cationic Azo Dye: Efficiency and Mechanism</title><source>American Society Of Civil Engineers ASCE Journals</source><creator>Yu, Peijing ; Fu, Fenglian</creator><creatorcontrib>Yu, Peijing ; Fu, Fenglian</creatorcontrib><description>AbstractMethylene blue (MB), a cationic azo dye, is harmful to the environment and human health. In this study, carbon microspheres (CMS)@magnetite was prepared to remove MB. The performance of CMS@magnetite on MB removal and adsorption mechanisms was studied. Transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller, X-ray diffraction, and vibrating-sample magnetometry were used to characterize the CMS@magnetite before and after adsorption with MB. The effects of different dosages and initial pH values on MB removal by CMS@magnetite were studied through batch experiments. Results reflected that CMS@magnetite had high removal efficiency on MB. In addition, adsorption isotherms, kinetics, and thermodynamics models were also studied. MB adsorption behavior was better described by the Langmuir model. The experimental data of MB adsorption by CMS@magnetite had a higher fitting degree with a pseudo-second-order kinetic model. In addition, reuse experiments were studied, which showed the advantage of good recycling ability of CMS@magnetite. MB was removed by CMS@magnetite through electrostatic adsorption and π-π interaction. Because of high removal efficiency, easy separation, and high performance of recycling, CMS@magnetite can be potentially used to remove MB wastewater.</description><identifier>ISSN: 0733-9372</identifier><identifier>EISSN: 1943-7870</identifier><identifier>DOI: 10.1061/(ASCE)EE.1943-7870.0001839</identifier><language>eng</language><publisher>New York: American Society of Civil Engineers</publisher><subject>Adsorption ; Azo dyes ; Carbon ; Cations ; Efficiency ; Electrostatic properties ; Fourier transforms ; Infrared spectroscopy ; Magnetic measurement ; Magnetite ; Methylene blue ; Microspheres ; Nanoparticles ; Photoelectron spectroscopy ; Photoelectrons ; Recycling ; Spectrum analysis ; Technical Papers ; Transmission electron microscopy ; Wastewater ; Wastewater treatment ; X ray photoelectron spectroscopy ; X-ray diffraction</subject><ispartof>Journal of environmental engineering (New York, N.Y.), 2021-02, Vol.147 (2)</ispartof><rights>2020 American Society of Civil Engineers</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a374t-b5e9b56ab1f35ff48a1be1368bc0f6c35076e025dd23ffc318b0d3ba0256a1293</citedby><cites>FETCH-LOGICAL-a374t-b5e9b56ab1f35ff48a1be1368bc0f6c35076e025dd23ffc318b0d3ba0256a1293</cites><orcidid>0000-0002-7495-5403</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttp://ascelibrary.org/doi/pdf/10.1061/(ASCE)EE.1943-7870.0001839$$EPDF$$P50$$Gasce$$H</linktopdf><linktohtml>$$Uhttp://ascelibrary.org/doi/abs/10.1061/(ASCE)EE.1943-7870.0001839$$EHTML$$P50$$Gasce$$H</linktohtml><link.rule.ids>314,778,782,3241,10051,27907,27908,75942,75950</link.rule.ids></links><search><creatorcontrib>Yu, Peijing</creatorcontrib><creatorcontrib>Fu, Fenglian</creatorcontrib><title>Application of Carbon Microsphere Loaded with Magnetite Nanoparticles for the Removal of a Cationic Azo Dye: Efficiency and Mechanism</title><title>Journal of environmental engineering (New York, N.Y.)</title><description>AbstractMethylene blue (MB), a cationic azo dye, is harmful to the environment and human health. In this study, carbon microspheres (CMS)@magnetite was prepared to remove MB. The performance of CMS@magnetite on MB removal and adsorption mechanisms was studied. Transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller, X-ray diffraction, and vibrating-sample magnetometry were used to characterize the CMS@magnetite before and after adsorption with MB. The effects of different dosages and initial pH values on MB removal by CMS@magnetite were studied through batch experiments. Results reflected that CMS@magnetite had high removal efficiency on MB. In addition, adsorption isotherms, kinetics, and thermodynamics models were also studied. MB adsorption behavior was better described by the Langmuir model. The experimental data of MB adsorption by CMS@magnetite had a higher fitting degree with a pseudo-second-order kinetic model. In addition, reuse experiments were studied, which showed the advantage of good recycling ability of CMS@magnetite. MB was removed by CMS@magnetite through electrostatic adsorption and π-π interaction. Because of high removal efficiency, easy separation, and high performance of recycling, CMS@magnetite can be potentially used to remove MB wastewater.</description><subject>Adsorption</subject><subject>Azo dyes</subject><subject>Carbon</subject><subject>Cations</subject><subject>Efficiency</subject><subject>Electrostatic properties</subject><subject>Fourier transforms</subject><subject>Infrared spectroscopy</subject><subject>Magnetic measurement</subject><subject>Magnetite</subject><subject>Methylene blue</subject><subject>Microspheres</subject><subject>Nanoparticles</subject><subject>Photoelectron spectroscopy</subject><subject>Photoelectrons</subject><subject>Recycling</subject><subject>Spectrum analysis</subject><subject>Technical Papers</subject><subject>Transmission electron microscopy</subject><subject>Wastewater</subject><subject>Wastewater treatment</subject><subject>X ray photoelectron spectroscopy</subject><subject>X-ray diffraction</subject><issn>0733-9372</issn><issn>1943-7870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kLFu2zAQhokiBeK6eQeiWdpBDilKlOTNcNS0gN0AbTITJ-oY0bBFlZQTuHveOxLspFOmOxz-7z_gI-QLZzPOJL_6uvizLL-V5YwXiYiyPGMzxhjPRfGBTN5uZ2TCMiGiQmTxOfkUwmbIJLLIJuR50XVbq6G3rqXO0CX4atjWVnsXugY90pWDGmv6ZPuGruGhxd72SH9B6zrwvdVbDNQ4T_sG6W_cuUfYjk0wdI2tVtPFP0evDzinpTFWW2z1gUJb0zXqBlobdp_JRwPbgBenOSX338u75Y9odXvzc7lYRSCypI-qFIsqlVBxI1Jjkhx4hVzIvNLMSC1SlklkcVrXsTBGC55XrBYVDCcJPC7ElFweezvv_u4x9Grj9r4dXqo4kbFIBiQeUvNjanQQPBrVebsDf1CcqVG7UqN2VZZqVKxGxeqkfYDlEYag8X_9K_k--AINdYfU</recordid><startdate>20210201</startdate><enddate>20210201</enddate><creator>Yu, Peijing</creator><creator>Fu, Fenglian</creator><general>American Society of Civil Engineers</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-7495-5403</orcidid></search><sort><creationdate>20210201</creationdate><title>Application of Carbon Microsphere Loaded with Magnetite Nanoparticles for the Removal of a Cationic Azo Dye: Efficiency and Mechanism</title><author>Yu, Peijing ; Fu, Fenglian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a374t-b5e9b56ab1f35ff48a1be1368bc0f6c35076e025dd23ffc318b0d3ba0256a1293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Adsorption</topic><topic>Azo dyes</topic><topic>Carbon</topic><topic>Cations</topic><topic>Efficiency</topic><topic>Electrostatic properties</topic><topic>Fourier transforms</topic><topic>Infrared spectroscopy</topic><topic>Magnetic measurement</topic><topic>Magnetite</topic><topic>Methylene blue</topic><topic>Microspheres</topic><topic>Nanoparticles</topic><topic>Photoelectron spectroscopy</topic><topic>Photoelectrons</topic><topic>Recycling</topic><topic>Spectrum analysis</topic><topic>Technical Papers</topic><topic>Transmission electron microscopy</topic><topic>Wastewater</topic><topic>Wastewater treatment</topic><topic>X ray photoelectron spectroscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, Peijing</creatorcontrib><creatorcontrib>Fu, Fenglian</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts – Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Journal of environmental engineering (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Peijing</au><au>Fu, Fenglian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of Carbon Microsphere Loaded with Magnetite Nanoparticles for the Removal of a Cationic Azo Dye: Efficiency and Mechanism</atitle><jtitle>Journal of environmental engineering (New York, N.Y.)</jtitle><date>2021-02-01</date><risdate>2021</risdate><volume>147</volume><issue>2</issue><issn>0733-9372</issn><eissn>1943-7870</eissn><abstract>AbstractMethylene blue (MB), a cationic azo dye, is harmful to the environment and human health. In this study, carbon microspheres (CMS)@magnetite was prepared to remove MB. The performance of CMS@magnetite on MB removal and adsorption mechanisms was studied. Transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller, X-ray diffraction, and vibrating-sample magnetometry were used to characterize the CMS@magnetite before and after adsorption with MB. The effects of different dosages and initial pH values on MB removal by CMS@magnetite were studied through batch experiments. Results reflected that CMS@magnetite had high removal efficiency on MB. In addition, adsorption isotherms, kinetics, and thermodynamics models were also studied. MB adsorption behavior was better described by the Langmuir model. The experimental data of MB adsorption by CMS@magnetite had a higher fitting degree with a pseudo-second-order kinetic model. In addition, reuse experiments were studied, which showed the advantage of good recycling ability of CMS@magnetite. MB was removed by CMS@magnetite through electrostatic adsorption and π-π interaction. Because of high removal efficiency, easy separation, and high performance of recycling, CMS@magnetite can be potentially used to remove MB wastewater.</abstract><cop>New York</cop><pub>American Society of Civil Engineers</pub><doi>10.1061/(ASCE)EE.1943-7870.0001839</doi><orcidid>https://orcid.org/0000-0002-7495-5403</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0733-9372
ispartof Journal of environmental engineering (New York, N.Y.), 2021-02, Vol.147 (2)
issn 0733-9372
1943-7870
language eng
recordid cdi_proquest_journals_2462343182
source American Society Of Civil Engineers ASCE Journals
subjects Adsorption
Azo dyes
Carbon
Cations
Efficiency
Electrostatic properties
Fourier transforms
Infrared spectroscopy
Magnetic measurement
Magnetite
Methylene blue
Microspheres
Nanoparticles
Photoelectron spectroscopy
Photoelectrons
Recycling
Spectrum analysis
Technical Papers
Transmission electron microscopy
Wastewater
Wastewater treatment
X ray photoelectron spectroscopy
X-ray diffraction
title Application of Carbon Microsphere Loaded with Magnetite Nanoparticles for the Removal of a Cationic Azo Dye: Efficiency and Mechanism
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T22%3A07%3A35IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Application%20of%20Carbon%20Microsphere%20Loaded%20with%20Magnetite%20Nanoparticles%20for%20the%20Removal%20of%20a%20Cationic%20Azo%20Dye:%20Efficiency%20and%20Mechanism&rft.jtitle=Journal%20of%20environmental%20engineering%20(New%20York,%20N.Y.)&rft.au=Yu,%20Peijing&rft.date=2021-02-01&rft.volume=147&rft.issue=2&rft.issn=0733-9372&rft.eissn=1943-7870&rft_id=info:doi/10.1061/(ASCE)EE.1943-7870.0001839&rft_dat=%3Cproquest_cross%3E2462343182%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a374t-b5e9b56ab1f35ff48a1be1368bc0f6c35076e025dd23ffc318b0d3ba0256a1293%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2462343182&rft_id=info:pmid/&rfr_iscdi=true