Glass bubble reinforced polyurethane foams with high mechanical strength for cryogenic temperature insulation

• Published in: Journal of applied polymer science 2021-03, Vol.138 (12), p.n/a
• Main Authors: Kim, Jeong‐Dae, Kim, Jeong‐Hyeon, Ahn, Jae‐Hyeok, Lee, Jae‐Myung
• Format: Article
• Language: English
• Subjects: Additives; Compression tests; Compressive strength; Cryogenic temperature; foams; Fourier transforms; Infrared analysis; Insulation; Materials science; Mechanical properties; Morphology; Nanoparticles; Plastic foam; Polymers; Polyurethane foam; Thermal conductivity; thermal properties; Thermodynamic properties; Weight
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.50060

In this study, glass bubble (GB) is added to polyurethane (PU) foams at different weight ratios—0, 0.25, 0.5, 0.75, and 1 wt% —to investigate the changes in the mechanical and thermal properties of the foam. By conducting several tests and measurements, the density, cell morphology, compressive strength, and thermal conductivity of the foam are studied. In particular, the effect of GB additives is examined by conducting compression tests at various temperatures (−163, −100, −40, and 20°C). Scanning electron microscopy and X‐ray microscope reveal that the foams exhibit higher stability below 0.5 wt%, which improves the thermal performance. On the other hand, the compressive strength of the foams increases for all weight ratios of GB, and it increases sharply at 0.75 wt%. In addition, the chemical interactions and the dispersion of additives in the PU matrix are investigated through Fourier transform infrared and X‐ray diffractions analysis. It is found that the synthesis of PU foams with GB nanoparticles is an efficient method for improving the mechanical properties and insulation performance of the foam for LNG insulation technology.