MOCVD growth of high purity Ga2O3 epitaxial films using trimethylgallium precursor

We report on the growth of β-Ga2O3 thin films using trimethylgallium (TMGa) as a source for gallium and pure O2 for oxidation. The growth rate of the films was found to linearly increase with the increase in the molar flow rate of TMGa and reach as high as ∼6 μm/h at a flow rate of 580 μmol/min. Hig...

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Bibliographic Details
Published in:Applied physics letters 2020-12, Vol.117 (26)
Main Authors: Seryogin, George, Alema, Fikadu, Valente, Nicholas, Fu, Houqiang, Steinbrunner, Erich, Neal, Adam T., Mou, Shin, Fine, Aaron, Osinsky, Andrei
Format: Article
Language:English
Subjects:
Applied physics
Carrier density
Electron mobility
Electronic devices
Electrons
Epitaxial growth
Field effect transistors
Flow velocity
Gallium oxides
Low temperature
Metalorganic chemical vapor deposition
Morphology
Oxidation
Precursors
Purity
Room temperature
Semiconductor devices
Silicon
Thin films
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Summary:We report on the growth of β-Ga2O3 thin films using trimethylgallium (TMGa) as a source for gallium and pure O2 for oxidation. The growth rate of the films was found to linearly increase with the increase in the molar flow rate of TMGa and reach as high as ∼6 μm/h at a flow rate of 580 μmol/min. High purity, lightly Si-doped homoepitaxial β-Ga2O3 films with a good surface morphology, a record low temperature electron mobility exceeding 23 000 cm2/V s at 32 K, and an acceptor concentration of 2 × 1013 cm−3 were realized, showing an excellent purity film. Films with room temperature (RT) electron mobilities ranging from 71 cm2/V s to 138 cm2/V s with the corresponding free carrier densities between ∼1.1 × 1019 cm−3 and ∼1.5 × 1016 were demonstrated. For layers with the doping concentration in the range of high-1017 and low-1018 cm−3, the RT electron mobility values were consistently more than 100 cm2/V s, suggesting that TMGa is suitable to grow channel layers for lateral devices, such as field effect transistors. The results demonstrate excellent purity of the films produced and confirm the suitability of the TMGa precursor for the growth of device quality β-Ga2O3 films at a fast growth rate, meeting the demands for commercializing Ga2O3-based high voltage power devices by metalorganic chemical vapor deposition.
ISSN:0003-6951
1077-3118
DOI:10.1063/5.0031484