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Investigation of the Chemical Interaction in the Sb2Te3–InSe System and the Properties of the Obtained Phases
The interaction in the Sb 2 Te 3 –InSe system was studied and the T–x phase diagram was constructed by integrated methods of physicochemical analysis (differential thermal, X-ray powder diffraction, and microstructural analyses) and also by microhardness and density measurements. It was found that t...
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| Published in: | Russian journal of inorganic chemistry 2020-10, Vol.65 (10), p.1585-1590 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c316t-93407ebebf1a7468b6f1a9f48ab6bf2af19297acba6235ee1d411e776b9729813 |
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| cites | cdi_FETCH-LOGICAL-c316t-93407ebebf1a7468b6f1a9f48ab6bf2af19297acba6235ee1d411e776b9729813 |
| container_end_page | 1590 |
| container_issue | 10 |
| container_start_page | 1585 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 65 |
| creator | Aliev, I. I. Mamedova, N. A. Sadygov, F. M. Sadygov, N. M. Melikova, I. G. |
| description | The interaction in the Sb
2
Te
3
–InSe system was studied and the
T–x
phase diagram was constructed by integrated methods of physicochemical analysis (differential thermal, X-ray powder diffraction, and microstructural analyses) and also by microhardness and density measurements. It was found that the Sb
2
Se
3
–InSe system is a quasi-binary section of the ternary reciprocal system Sb,In||Se,Te. In the Sb
2
Te
3
–InSe system, compounds InSb
2
SeTe
3
and In
3
Sb
2
Se
3
Te
3
form, which incongruently melt at 525 and 600°C, respectively. It was found that the regions of solid solutions based on Sb
2
Te
3
and InSe extend to 3 and 2 mol %, respectively. The compounds Sb
2
Se
3
and InSe form a eutectic with the coordinates 20 mol % InSe and 510°C. The temperature dependences of the electrical conductivity and thermal emf of the solid solutions (Sb
2
Te
3
)
1 –
x
(InSe)
x
(
x
= 0.01, 0.02, and 0.03). |
| doi_str_mv | 10.1134/S0036023620100010 |
| format | article |
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2
Te
3
–InSe system was studied and the
T–x
phase diagram was constructed by integrated methods of physicochemical analysis (differential thermal, X-ray powder diffraction, and microstructural analyses) and also by microhardness and density measurements. It was found that the Sb
2
Se
3
–InSe system is a quasi-binary section of the ternary reciprocal system Sb,In||Se,Te. In the Sb
2
Te
3
–InSe system, compounds InSb
2
SeTe
3
and In
3
Sb
2
Se
3
Te
3
form, which incongruently melt at 525 and 600°C, respectively. It was found that the regions of solid solutions based on Sb
2
Te
3
and InSe extend to 3 and 2 mol %, respectively. The compounds Sb
2
Se
3
and InSe form a eutectic with the coordinates 20 mol % InSe and 510°C. The temperature dependences of the electrical conductivity and thermal emf of the solid solutions (Sb
2
Te
3
)
1 –
x
(InSe)
x
(
x
= 0.01, 0.02, and 0.03).</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023620100010</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Antimony ; Antimony compounds ; Antimony telluride ; Chemistry ; Chemistry and Materials Science ; Differential thermal analysis ; Electrical resistivity ; Inorganic Chemistry ; Microhardness ; Phase diagrams ; Physicochemical Analysis of Inorganic Systems ; Selenides ; Solid solutions ; Tellurium ; X ray powder diffraction</subject><ispartof>Russian journal of inorganic chemistry, 2020-10, Vol.65 (10), p.1585-1590</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-93407ebebf1a7468b6f1a9f48ab6bf2af19297acba6235ee1d411e776b9729813</citedby><cites>FETCH-LOGICAL-c316t-93407ebebf1a7468b6f1a9f48ab6bf2af19297acba6235ee1d411e776b9729813</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Aliev, I. I.</creatorcontrib><creatorcontrib>Mamedova, N. A.</creatorcontrib><creatorcontrib>Sadygov, F. M.</creatorcontrib><creatorcontrib>Sadygov, N. M.</creatorcontrib><creatorcontrib>Melikova, I. G.</creatorcontrib><title>Investigation of the Chemical Interaction in the Sb2Te3–InSe System and the Properties of the Obtained Phases</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The interaction in the Sb
2
Te
3
–InSe system was studied and the
T–x
phase diagram was constructed by integrated methods of physicochemical analysis (differential thermal, X-ray powder diffraction, and microstructural analyses) and also by microhardness and density measurements. It was found that the Sb
2
Se
3
–InSe system is a quasi-binary section of the ternary reciprocal system Sb,In||Se,Te. In the Sb
2
Te
3
–InSe system, compounds InSb
2
SeTe
3
and In
3
Sb
2
Se
3
Te
3
form, which incongruently melt at 525 and 600°C, respectively. It was found that the regions of solid solutions based on Sb
2
Te
3
and InSe extend to 3 and 2 mol %, respectively. The compounds Sb
2
Se
3
and InSe form a eutectic with the coordinates 20 mol % InSe and 510°C. The temperature dependences of the electrical conductivity and thermal emf of the solid solutions (Sb
2
Te
3
)
1 –
x
(InSe)
x
(
x
= 0.01, 0.02, and 0.03).</description><subject>Antimony</subject><subject>Antimony compounds</subject><subject>Antimony telluride</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Differential thermal analysis</subject><subject>Electrical resistivity</subject><subject>Inorganic Chemistry</subject><subject>Microhardness</subject><subject>Phase diagrams</subject><subject>Physicochemical Analysis of Inorganic Systems</subject><subject>Selenides</subject><subject>Solid solutions</subject><subject>Tellurium</subject><subject>X ray powder diffraction</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kM9KAzEQxoMoWKsP4G3B82om2SaboxT_LBRaaD0vyXa23dJma5IKvfkOvqFPYrpVPIiHMAm_7_smM4RcA70F4NndlFIuKOOCUaA0nhPSgwGHNBfAT0nvgNMDPycX3q8ozTIq8x5pC_uGPjQLHZrWJm2dhCUmwyVumkqvk8IGdLrqWGM7NjVshvzz_aOw0_ja-4CbRNt5Byeu3aILDfqfqLEJurE4TyZL7dFfkrNarz1efdc-eXl8mA2f09H4qRjej9KKgwip4vF7aNDUoGUmciPiRdVZro0wNdM1KKakrowWjA8QYZ4BoJTCKMlUDrxPbo65W9e-7uKE5ardORtbliyTXCoGnQqOqsq13jusy61rNtrtS6DlYa_ln71GDzt6fNTaBbrf5P9NXyNsegQ</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Aliev, I. I.</creator><creator>Mamedova, N. A.</creator><creator>Sadygov, F. M.</creator><creator>Sadygov, N. M.</creator><creator>Melikova, I. G.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20201001</creationdate><title>Investigation of the Chemical Interaction in the Sb2Te3–InSe System and the Properties of the Obtained Phases</title><author>Aliev, I. I. ; Mamedova, N. A. ; Sadygov, F. M. ; Sadygov, N. M. ; Melikova, I. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-93407ebebf1a7468b6f1a9f48ab6bf2af19297acba6235ee1d411e776b9729813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Antimony</topic><topic>Antimony compounds</topic><topic>Antimony telluride</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Differential thermal analysis</topic><topic>Electrical resistivity</topic><topic>Inorganic Chemistry</topic><topic>Microhardness</topic><topic>Phase diagrams</topic><topic>Physicochemical Analysis of Inorganic Systems</topic><topic>Selenides</topic><topic>Solid solutions</topic><topic>Tellurium</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aliev, I. I.</creatorcontrib><creatorcontrib>Mamedova, N. A.</creatorcontrib><creatorcontrib>Sadygov, F. M.</creatorcontrib><creatorcontrib>Sadygov, N. M.</creatorcontrib><creatorcontrib>Melikova, I. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aliev, I. I.</au><au>Mamedova, N. A.</au><au>Sadygov, F. M.</au><au>Sadygov, N. M.</au><au>Melikova, I. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of the Chemical Interaction in the Sb2Te3–InSe System and the Properties of the Obtained Phases</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2020-10-01</date><risdate>2020</risdate><volume>65</volume><issue>10</issue><spage>1585</spage><epage>1590</epage><pages>1585-1590</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The interaction in the Sb
2
Te
3
–InSe system was studied and the
T–x
phase diagram was constructed by integrated methods of physicochemical analysis (differential thermal, X-ray powder diffraction, and microstructural analyses) and also by microhardness and density measurements. It was found that the Sb
2
Se
3
–InSe system is a quasi-binary section of the ternary reciprocal system Sb,In||Se,Te. In the Sb
2
Te
3
–InSe system, compounds InSb
2
SeTe
3
and In
3
Sb
2
Se
3
Te
3
form, which incongruently melt at 525 and 600°C, respectively. It was found that the regions of solid solutions based on Sb
2
Te
3
and InSe extend to 3 and 2 mol %, respectively. The compounds Sb
2
Se
3
and InSe form a eutectic with the coordinates 20 mol % InSe and 510°C. The temperature dependences of the electrical conductivity and thermal emf of the solid solutions (Sb
2
Te
3
)
1 –
x
(InSe)
x
(
x
= 0.01, 0.02, and 0.03).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023620100010</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2020-10, Vol.65 (10), p.1585-1590 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_journals_2473792181 |
| source | Springer Nature |
| subjects | Antimony Antimony compounds Antimony telluride Chemistry Chemistry and Materials Science Differential thermal analysis Electrical resistivity Inorganic Chemistry Microhardness Phase diagrams Physicochemical Analysis of Inorganic Systems Selenides Solid solutions Tellurium X ray powder diffraction |
| title | Investigation of the Chemical Interaction in the Sb2Te3–InSe System and the Properties of the Obtained Phases |
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